Organoactinide-Catalyzed Monohydroboration of Carbodiimides

Heng Liu; Kseniya Kulbitski; Matthias Tamm; Moris S. Eisen

doi:10.1002/chem.201705987

Organoactinide-Catalyzed Monohydroboration of Carbodiimides

Heng Liu, Kseniya Kulbitski, Matthias Tamm^*, Moris S. Eisen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

The organoactinide-catalyzed monohydroboration of carbodiimides is reported herein. The catalytic reactions proceed under very mild conditions in a highly atom-efficient and highly selective fashion to afford the corresponding monohydroborated N-borylformamidine products in high yields. A plausible mechanism is proposed based on stoichiometric and kinetic studies.

Original language	English
Pages (from-to)	5738-5742
Number of pages	5
Journal	Chemistry - A European Journal
Volume	24
Issue number	22
DOIs	https://doi.org/10.1002/chem.201705987
State	Published - 17 Apr 2018
Externally published	Yes

Keywords

actinides
boron
carbodiimide
hydroboration
organoactinide

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title = "Organoactinide-Catalyzed Monohydroboration of Carbodiimides",

abstract = "The organoactinide-catalyzed monohydroboration of carbodiimides is reported herein. The catalytic reactions proceed under very mild conditions in a highly atom-efficient and highly selective fashion to afford the corresponding monohydroborated N-borylformamidine products in high yields. A plausible mechanism is proposed based on stoichiometric and kinetic studies.",

keywords = "actinides, boron, carbodiimide, hydroboration, organoactinide",

author = "Heng Liu and Kseniya Kulbitski and Matthias Tamm and Eisen, {Moris S.}",

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T1 - Organoactinide-Catalyzed Monohydroboration of Carbodiimides

AU - Liu, Heng

AU - Kulbitski, Kseniya

AU - Tamm, Matthias

AU - Eisen, Moris S.

PY - 2018/4/17

Y1 - 2018/4/17

N2 - The organoactinide-catalyzed monohydroboration of carbodiimides is reported herein. The catalytic reactions proceed under very mild conditions in a highly atom-efficient and highly selective fashion to afford the corresponding monohydroborated N-borylformamidine products in high yields. A plausible mechanism is proposed based on stoichiometric and kinetic studies.

AB - The organoactinide-catalyzed monohydroboration of carbodiimides is reported herein. The catalytic reactions proceed under very mild conditions in a highly atom-efficient and highly selective fashion to afford the corresponding monohydroborated N-borylformamidine products in high yields. A plausible mechanism is proposed based on stoichiometric and kinetic studies.

KW - actinides

KW - boron

KW - carbodiimide

KW - hydroboration

KW - organoactinide

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U2 - 10.1002/chem.201705987

DO - 10.1002/chem.201705987

M3 - 文章

C2 - 29465797

AN - SCOPUS:85044176110

SN - 0947-6539

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JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 22

ER -

Organoactinide-Catalyzed Monohydroboration of Carbodiimides

Abstract

Keywords

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