Organoactinide-Catalyzed Monohydroboration of Carbodiimides

Heng Liu, Kseniya Kulbitski, Matthias Tamm*, Moris S. Eisen

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

19 Scopus citations

Abstract

The organoactinide-catalyzed monohydroboration of carbodiimides is reported herein. The catalytic reactions proceed under very mild conditions in a highly atom-efficient and highly selective fashion to afford the corresponding monohydroborated N-borylformamidine products in high yields. A plausible mechanism is proposed based on stoichiometric and kinetic studies.

Original languageEnglish
Pages (from-to)5738-5742
Number of pages5
JournalChemistry - A European Journal
Volume24
Issue number22
DOIs
StatePublished - 17 Apr 2018
Externally publishedYes

Keywords

  • actinides
  • boron
  • carbodiimide
  • hydroboration
  • organoactinide

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