TY - JOUR
T1 - Enhancing preferential oxidation of CO in H2 on Au/α-Fe2O3 catalyst via combination with APTES/SBA-15 CO2-sorbent
AU - Desmond Ng, Jia Wei
AU - Zhong, Ziyi
AU - Luo, Jizhong
AU - Borgna, Armando
N1 - Copyright:
Copyright 2013 Elsevier B.V., All rights reserved.
PY - 2010/12
Y1 - 2010/12
N2 - Au/α-Fe2O3 was combined with a CO 2-sorbent (3-aminopropyltriethoxysilane (APTES) grafted on SBA-15 and hereafter denoted as APTES/SBA-15) to enhance preferential oxidation (PROX) of CO in H2. The CO2 molecules could be rapidly adsorbed on APTES/SBA-15 at low temperatures below 50 °C with a capacity of 0.68 mmol CO2/g-sample, and desorbed at a temperature range of 50 °C-80 °C. Three different configurations of the Au/α-Fe2O 3 catalyst and the CO2-sorbent were tested in the PROX reaction, namely (i) the sorbent-free (catalyst//SBA-15//catalyst) configuration, (ii) the packed three-layer configuration (catalyst//CO 2-sorbent//catalyst), and (iii) the mechanically mixed catalyst and CO2-sorbent configuration. Compared to configuration (i), configuration (ii) achieved an average 10% higher CO conversion at 50 °C and a GHSV of 65000 h-1. However, the CO concentration could not be lowered to below 70 ppm from 2000 ppm using configuration (ii) at a GHSV of 10000 h-1. Thus, a 5-layer configuration (catalyst//CO 2-sorbent//catalyst//CO2-sorbent//catalyst) was used, and the CO concentration was lowered to ca. 25 ppm. The mechanism for enhancement of the PROX reaction by the continuous removal of CO2 by the CO 2-sorbent is discussed and attributed to reduction of the surface carbonate on the Au/α-Fe2O3 catalyst formed during the PROX process.
AB - Au/α-Fe2O3 was combined with a CO 2-sorbent (3-aminopropyltriethoxysilane (APTES) grafted on SBA-15 and hereafter denoted as APTES/SBA-15) to enhance preferential oxidation (PROX) of CO in H2. The CO2 molecules could be rapidly adsorbed on APTES/SBA-15 at low temperatures below 50 °C with a capacity of 0.68 mmol CO2/g-sample, and desorbed at a temperature range of 50 °C-80 °C. Three different configurations of the Au/α-Fe2O 3 catalyst and the CO2-sorbent were tested in the PROX reaction, namely (i) the sorbent-free (catalyst//SBA-15//catalyst) configuration, (ii) the packed three-layer configuration (catalyst//CO 2-sorbent//catalyst), and (iii) the mechanically mixed catalyst and CO2-sorbent configuration. Compared to configuration (i), configuration (ii) achieved an average 10% higher CO conversion at 50 °C and a GHSV of 65000 h-1. However, the CO concentration could not be lowered to below 70 ppm from 2000 ppm using configuration (ii) at a GHSV of 10000 h-1. Thus, a 5-layer configuration (catalyst//CO 2-sorbent//catalyst//CO2-sorbent//catalyst) was used, and the CO concentration was lowered to ca. 25 ppm. The mechanism for enhancement of the PROX reaction by the continuous removal of CO2 by the CO 2-sorbent is discussed and attributed to reduction of the surface carbonate on the Au/α-Fe2O3 catalyst formed during the PROX process.
KW - CO-sorbent
KW - Functionalized SBA-15
KW - PROX reaction
KW - Supported Au catalysts
UR - http://www.scopus.com/inward/record.url?scp=78049468673&partnerID=8YFLogxK
U2 - 10.1016/j.ijhydene.2010.08.136
DO - 10.1016/j.ijhydene.2010.08.136
M3 - 文章
AN - SCOPUS:78049468673
VL - 35
SP - 12724
EP - 12732
JO - International Journal of Hydrogen Energy
JF - International Journal of Hydrogen Energy
SN - 0360-3199
IS - 23
ER -