Catalytic insertion of E-H bonds (E = C, N, P, S) into heterocumulenes by amido-actinide complexes

Rami J. Batrice; Moris S. Eisen

doi:10.1039/c5sc02746b

Catalytic insertion of E-H bonds (E = C, N, P, S) into heterocumulenes by amido-actinide complexes

Rami J. Batrice, Moris S. Eisen^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

We report herein the actinide-mediated insertion of E-H bonds (E = C, N, P, S) into various heterocumulenes including carbodiimides, isocyanates, and isothiocyanates. The precatalysts are prepared by a simple, one-pot procedure using readily available starting materials, and challenging insertions are achieved with excellent selectivity in short reaction times. Spectroscopic data are utilised to propose the active catalytic mechanism and derive thermodynamic activation parameters, which are described in this study. The only example of an actinide-mediated C-H bond insertion into a carbon-heteroatom bond is presented within this study.

Original language	English
Pages (from-to)	939-944
Number of pages	6
Journal	Chemical Science
Volume	7
Issue number	2
DOIs	https://doi.org/10.1039/c5sc02746b
State	Published - 2016
Externally published	Yes

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title = "Catalytic insertion of E-H bonds (E = C, N, P, S) into heterocumulenes by amido-actinide complexes",

abstract = "We report herein the actinide-mediated insertion of E-H bonds (E = C, N, P, S) into various heterocumulenes including carbodiimides, isocyanates, and isothiocyanates. The precatalysts are prepared by a simple, one-pot procedure using readily available starting materials, and challenging insertions are achieved with excellent selectivity in short reaction times. Spectroscopic data are utilised to propose the active catalytic mechanism and derive thermodynamic activation parameters, which are described in this study. The only example of an actinide-mediated C-H bond insertion into a carbon-heteroatom bond is presented within this study.",

author = "Batrice, {Rami J.} and Eisen, {Moris S.}",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c5sc02746b",

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journal = "Chemical Science",

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T1 - Catalytic insertion of E-H bonds (E = C, N, P, S) into heterocumulenes by amido-actinide complexes

AU - Batrice, Rami J.

AU - Eisen, Moris S.

PY - 2016

Y1 - 2016

N2 - We report herein the actinide-mediated insertion of E-H bonds (E = C, N, P, S) into various heterocumulenes including carbodiimides, isocyanates, and isothiocyanates. The precatalysts are prepared by a simple, one-pot procedure using readily available starting materials, and challenging insertions are achieved with excellent selectivity in short reaction times. Spectroscopic data are utilised to propose the active catalytic mechanism and derive thermodynamic activation parameters, which are described in this study. The only example of an actinide-mediated C-H bond insertion into a carbon-heteroatom bond is presented within this study.

AB - We report herein the actinide-mediated insertion of E-H bonds (E = C, N, P, S) into various heterocumulenes including carbodiimides, isocyanates, and isothiocyanates. The precatalysts are prepared by a simple, one-pot procedure using readily available starting materials, and challenging insertions are achieved with excellent selectivity in short reaction times. Spectroscopic data are utilised to propose the active catalytic mechanism and derive thermodynamic activation parameters, which are described in this study. The only example of an actinide-mediated C-H bond insertion into a carbon-heteroatom bond is presented within this study.

UR - http://www.scopus.com/inward/record.url?scp=84961287793&partnerID=8YFLogxK

U2 - 10.1039/c5sc02746b

DO - 10.1039/c5sc02746b

M3 - 文章

AN - SCOPUS:84961287793

SN - 2041-6520

VL - 7

SP - 939

EP - 944

JO - Chemical Science

JF - Chemical Science

IS - 2

ER -

Catalytic insertion of E-H bonds (E = C, N, P, S) into heterocumulenes by amido-actinide complexes

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