Triple Mukaiyama-Michael cascade toward a tricyclic framework

Dina Shpasser; Moshe Kapon; Mark Botoshansky; Moris S. Eisen

doi:10.1055/s-0030-1260161

Triple Mukaiyama-Michael cascade toward a tricyclic framework

Dina Shpasser, Moshe Kapon, Mark Botoshansky, Moris S. Eisen^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The intermolecular Mukaiyama-Michael addition between stoichiometric amounts of a bisketene acetal and methyl vinyl ketone is rapidly followed by a double cascade intramolecular Mukaiyama-Michael addition to form a fused tricyclic compound containing four-, five- and six-membered rings embellished with several functionalities.

Original language	English
Article number	Z45111SS
Pages (from-to)	2751-2753
Number of pages	3
Journal	Synthesis
Issue number	17
DOIs	https://doi.org/10.1055/s-0030-1260161
State	Published - 2011
Externally published	Yes

Keywords

Mukaiyama-Michael addition
bisketene acetals
cascade reaction
fused tricyclic framework
silyl enol ethers

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10.1055/s-0030-1260161

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title = "Triple Mukaiyama-Michael cascade toward a tricyclic framework",

abstract = "The intermolecular Mukaiyama-Michael addition between stoichiometric amounts of a bisketene acetal and methyl vinyl ketone is rapidly followed by a double cascade intramolecular Mukaiyama-Michael addition to form a fused tricyclic compound containing four-, five- and six-membered rings embellished with several functionalities.",

keywords = "Mukaiyama-Michael addition, bisketene acetals, cascade reaction, fused tricyclic framework, silyl enol ethers",

author = "Dina Shpasser and Moshe Kapon and Mark Botoshansky and Eisen, {Moris S.}",

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AU - Shpasser, Dina

AU - Kapon, Moshe

AU - Botoshansky, Mark

AU - Eisen, Moris S.

PY - 2011

Y1 - 2011

N2 - The intermolecular Mukaiyama-Michael addition between stoichiometric amounts of a bisketene acetal and methyl vinyl ketone is rapidly followed by a double cascade intramolecular Mukaiyama-Michael addition to form a fused tricyclic compound containing four-, five- and six-membered rings embellished with several functionalities.

AB - The intermolecular Mukaiyama-Michael addition between stoichiometric amounts of a bisketene acetal and methyl vinyl ketone is rapidly followed by a double cascade intramolecular Mukaiyama-Michael addition to form a fused tricyclic compound containing four-, five- and six-membered rings embellished with several functionalities.

KW - Mukaiyama-Michael addition

KW - bisketene acetals

KW - cascade reaction

KW - fused tricyclic framework

KW - silyl enol ethers

UR - http://www.scopus.com/inward/record.url?scp=80052071801&partnerID=8YFLogxK

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DO - 10.1055/s-0030-1260161

M3 - 文章

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EP - 2753

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JF - Synthesis

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M1 - Z45111SS

ER -

Triple Mukaiyama-Michael cascade toward a tricyclic framework

Abstract

Keywords

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