Thorium complexes possessing expanded ring N-heterocyclic iminato ligands: Synthesis and applications

Tapas Ghatak; Shani Drucker; Natalia Fridman; Moris S. Eisen

doi:10.1039/c7dt02126g

Thorium complexes possessing expanded ring N-heterocyclic iminato ligands: Synthesis and applications

Tapas Ghatak, Shani Drucker, Natalia Fridman, Moris S. Eisen^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

Six and seven membered N-heterocyclic iminato ligands (L) are introduced allowing access a new class of Th(iv) complexes of the type Cp∗₂Th(L)(CH₃). These complexes were studied in the Tishchenko reaction. Stoichiometric reactions together with kinetic and thermodynamic studies permit us to propose a plausible mechanism.

Original language	English
Pages (from-to)	12005-12009
Number of pages	5
Journal	Dalton Transactions
Volume	46
Issue number	36
DOIs	https://doi.org/10.1039/c7dt02126g
State	Published - 2017
Externally published	Yes

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title = "Thorium complexes possessing expanded ring N-heterocyclic iminato ligands: Synthesis and applications",

abstract = "Six and seven membered N-heterocyclic iminato ligands (L) are introduced allowing access a new class of Th(iv) complexes of the type Cp∗2Th(L)(CH3). These complexes were studied in the Tishchenko reaction. Stoichiometric reactions together with kinetic and thermodynamic studies permit us to propose a plausible mechanism.",

author = "Tapas Ghatak and Shani Drucker and Natalia Fridman and Eisen, {Moris S.}",

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T1 - Thorium complexes possessing expanded ring N-heterocyclic iminato ligands

T2 - Synthesis and applications

AU - Ghatak, Tapas

AU - Drucker, Shani

AU - Fridman, Natalia

AU - Eisen, Moris S.

PY - 2017

Y1 - 2017

N2 - Six and seven membered N-heterocyclic iminato ligands (L) are introduced allowing access a new class of Th(iv) complexes of the type Cp∗2Th(L)(CH3). These complexes were studied in the Tishchenko reaction. Stoichiometric reactions together with kinetic and thermodynamic studies permit us to propose a plausible mechanism.

AB - Six and seven membered N-heterocyclic iminato ligands (L) are introduced allowing access a new class of Th(iv) complexes of the type Cp∗2Th(L)(CH3). These complexes were studied in the Tishchenko reaction. Stoichiometric reactions together with kinetic and thermodynamic studies permit us to propose a plausible mechanism.

UR - http://www.scopus.com/inward/record.url?scp=85029664339&partnerID=8YFLogxK

U2 - 10.1039/c7dt02126g

DO - 10.1039/c7dt02126g

M3 - 文章

C2 - 28678261

AN - SCOPUS:85029664339

SN - 1477-9226

VL - 46

SP - 12005

EP - 12009

JO - Dalton Transactions

JF - Dalton Transactions

IS - 36

ER -

Thorium complexes possessing expanded ring N-heterocyclic iminato ligands: Synthesis and applications

Abstract

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