Photochemical study of anthracene crystallites by fourier transform spectroscopic imaging

Chanan Sluszny; Valery Bulatov; Vladimir V. Gridin; Israel Schechter

doi:10.1562/0031-8655(2001)074<0780:PSOACB>2.0.CO;2

Photochemical study of anthracene crystallites by fourier transform spectroscopic imaging

Chanan Sluszny, Valery Bulatov, Vladimir V. Gridin, Israel Schechter^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Fourier transform-based spectroscopic imaging was used for direct, time-resolved, analysis of UV-irradiated anthracene crystallites. Well-resolved fluorescence spectra were obtained at a spatial resolution of 1 μm. The appearance of such photochemical by-products as dianthracene and anthraquinone was monitored throughout the irradiation experiments. Under deaerated conditions, photolysis of anthracene was accompanied by formation of dianthracene. When performed under aerated conditions, however, the spectral data indicated formation of both dianthracene and anthraquinone. Spectral features obtained for the directly monitored photolysis of anthracene are discussed in respect to the structural and compositional modifications in such crystallites. Capabilities of the spectral imaging device for the quantification of the photochemical products of anthracene are discussed.

Original language	English
Pages (from-to)	780-786
Number of pages	7
Journal	Photochemistry and Photobiology
Volume	74
Issue number	6
DOIs	https://doi.org/10.1562/0031-8655(2001)074<0780:PSOACB>2.0.CO;2
State	Published - 1 Dec 2001
Externally published	Yes

Access to Document

10.1562/0031-8655(2001)074<0780:PSOACB>2.0.CO;2

Cite this

@article{bea823cec5bb45b68b54eb50cf46e05e,

title = "Photochemical study of anthracene crystallites by fourier transform spectroscopic imaging",

abstract = "Fourier transform-based spectroscopic imaging was used for direct, time-resolved, analysis of UV-irradiated anthracene crystallites. Well-resolved fluorescence spectra were obtained at a spatial resolution of 1 μm. The appearance of such photochemical by-products as dianthracene and anthraquinone was monitored throughout the irradiation experiments. Under deaerated conditions, photolysis of anthracene was accompanied by formation of dianthracene. When performed under aerated conditions, however, the spectral data indicated formation of both dianthracene and anthraquinone. Spectral features obtained for the directly monitored photolysis of anthracene are discussed in respect to the structural and compositional modifications in such crystallites. Capabilities of the spectral imaging device for the quantification of the photochemical products of anthracene are discussed.",

author = "Chanan Sluszny and Valery Bulatov and Gridin, {Vladimir V.} and Israel Schechter",

year = "2001",

month = dec,

day = "1",

doi = "10.1562/0031-8655(2001)074<0780:PSOACB>2.0.CO;2",

language = "英语",

volume = "74",

pages = "780--786",

journal = "Photochemistry and Photobiology",

issn = "0031-8655",

publisher = "Wiley-Blackwell",

number = "6",

}

TY - JOUR

T1 - Photochemical study of anthracene crystallites by fourier transform spectroscopic imaging

AU - Sluszny, Chanan

AU - Bulatov, Valery

AU - Gridin, Vladimir V.

AU - Schechter, Israel

PY - 2001/12/1

Y1 - 2001/12/1

N2 - Fourier transform-based spectroscopic imaging was used for direct, time-resolved, analysis of UV-irradiated anthracene crystallites. Well-resolved fluorescence spectra were obtained at a spatial resolution of 1 μm. The appearance of such photochemical by-products as dianthracene and anthraquinone was monitored throughout the irradiation experiments. Under deaerated conditions, photolysis of anthracene was accompanied by formation of dianthracene. When performed under aerated conditions, however, the spectral data indicated formation of both dianthracene and anthraquinone. Spectral features obtained for the directly monitored photolysis of anthracene are discussed in respect to the structural and compositional modifications in such crystallites. Capabilities of the spectral imaging device for the quantification of the photochemical products of anthracene are discussed.

AB - Fourier transform-based spectroscopic imaging was used for direct, time-resolved, analysis of UV-irradiated anthracene crystallites. Well-resolved fluorescence spectra were obtained at a spatial resolution of 1 μm. The appearance of such photochemical by-products as dianthracene and anthraquinone was monitored throughout the irradiation experiments. Under deaerated conditions, photolysis of anthracene was accompanied by formation of dianthracene. When performed under aerated conditions, however, the spectral data indicated formation of both dianthracene and anthraquinone. Spectral features obtained for the directly monitored photolysis of anthracene are discussed in respect to the structural and compositional modifications in such crystallites. Capabilities of the spectral imaging device for the quantification of the photochemical products of anthracene are discussed.

UR - http://www.scopus.com/inward/record.url?scp=0035790053&partnerID=8YFLogxK

U2 - 10.1562/0031-8655(2001)074<0780:PSOACB>2.0.CO;2

DO - 10.1562/0031-8655(2001)074<0780:PSOACB>2.0.CO;2

M3 - 文章

C2 - 11783933

AN - SCOPUS:0035790053

SN - 0031-8655

VL - 74

SP - 780

EP - 786

JO - Photochemistry and Photobiology

JF - Photochemistry and Photobiology

IS - 6

ER -

Photochemical study of anthracene crystallites by fourier transform spectroscopic imaging

Abstract

Access to Document

Other files and links

Fingerprint

Cite this