TY - JOUR
T1 - Novel leaflike Cu-O-Sn nanosheets as highly efficient catalysts for the Rochow reaction
AU - Zou, Shanying
AU - Ji, Yongjun
AU - Li, Jing
AU - Zhang, Yu
AU - Jin, Zheying
AU - Jia, Lihua
AU - Guo, Xiangfeng
AU - Zhong, Ziyi
AU - Su, Fabing
N1 - Publisher Copyright:
© 2016 Elsevier Inc. All rights reserved.
PY - 2016/5/1
Y1 - 2016/5/1
N2 - In this work, we report the preparation of novel leaflike Cu-O-Sn nanosheet catalysts for the Rochow reaction. The catalysts were synthesized via a facile hydrothermal approach using CuSO4·3H2O and SnCl4·5H2O as the precursors, but without the use of any template. When used for the Rochow reaction to synthesize dimethyldichlorosilane (M2), the as-prepared 0.1 wt.% Cu-O-Sn nanosheet exhibited a much higher M2 selectivity (93.3%), Si conversion (68.4%), and stability than the catalysts of CuO or SnO2 alone, the Cu-O-Sn catalysts with different compositions, and the commercial catalysts. The samples were characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, atomic force microscopy, Raman spectroscopy, X-ray photoelectron spectroscopy, and temperature-programmed reduction analyses. Surface segregation of Sn was observed, and the quantities of chemisorbed oxygen species and cation vacancies were well correlated with the activity of the catalysts. It is concluded that small crystal size, high chemisorbed oxygen species concentration, more cation vacancies, and strong interaction between Cu and Sn are responsible for the excellent catalytic performance of 0.1 wt.% Cu-O-Sn catalyst.
AB - In this work, we report the preparation of novel leaflike Cu-O-Sn nanosheet catalysts for the Rochow reaction. The catalysts were synthesized via a facile hydrothermal approach using CuSO4·3H2O and SnCl4·5H2O as the precursors, but without the use of any template. When used for the Rochow reaction to synthesize dimethyldichlorosilane (M2), the as-prepared 0.1 wt.% Cu-O-Sn nanosheet exhibited a much higher M2 selectivity (93.3%), Si conversion (68.4%), and stability than the catalysts of CuO or SnO2 alone, the Cu-O-Sn catalysts with different compositions, and the commercial catalysts. The samples were characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, atomic force microscopy, Raman spectroscopy, X-ray photoelectron spectroscopy, and temperature-programmed reduction analyses. Surface segregation of Sn was observed, and the quantities of chemisorbed oxygen species and cation vacancies were well correlated with the activity of the catalysts. It is concluded that small crystal size, high chemisorbed oxygen species concentration, more cation vacancies, and strong interaction between Cu and Sn are responsible for the excellent catalytic performance of 0.1 wt.% Cu-O-Sn catalyst.
KW - Composite oxide
KW - Cu-based catalysts
KW - Hydrothermal method
KW - Nanosheet
KW - Rochow reaction
UR - http://www.scopus.com/inward/record.url?scp=84957865891&partnerID=8YFLogxK
U2 - 10.1016/j.jcat.2016.01.009
DO - 10.1016/j.jcat.2016.01.009
M3 - 文章
AN - SCOPUS:84957865891
SN - 0021-9517
VL - 337
SP - 1
EP - 13
JO - Journal of Catalysis
JF - Journal of Catalysis
ER -