Experimental study of bifurcation diagrams and maps of two parallel interacting catalytic reactions

R. R. Xiao; M. Sheintuch; D. Luss

doi:10.1016/0009-2509(86)87125-1

Experimental study of bifurcation diagrams and maps of two parallel interacting catalytic reactions

R. R. Xiao^*, M. Sheintuch, D. Luss

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Steady state multiplicity features of systems in which two reactions occur simultaneously may be affected by thermal and kinetic interactions and be qualitatively different from those of a single reaction. This is illustrated by an experimental study of the catalytic co-oxidation of hydrogen with either ammonia, butane or ethylene on a Pt wire. The bifurcation diagrams of wire temperature at a fixed hydrogen concentration vs. co-reactant concentration reveal multiplicity features which cannot be accounted for just by thermal interaction. The ignited branch was discontinuous at intermediate H₂ concentrations and extinction occurred upon increasing the co-reactant concentration. The loci of the observed ignition and extinction points were used to construct a bifurcation map in the concentration plane. The maps show that kinetic inhibition exists between the two reactions in addition to thermal interaction.

Original language	English
Pages (from-to)	2085-2092
Number of pages	8
Journal	Chemical Engineering Science
Volume	41
Issue number	8
DOIs	https://doi.org/10.1016/0009-2509(86)87125-1
State	Published - 1986
Externally published	Yes

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title = "Experimental study of bifurcation diagrams and maps of two parallel interacting catalytic reactions",

abstract = "Steady state multiplicity features of systems in which two reactions occur simultaneously may be affected by thermal and kinetic interactions and be qualitatively different from those of a single reaction. This is illustrated by an experimental study of the catalytic co-oxidation of hydrogen with either ammonia, butane or ethylene on a Pt wire. The bifurcation diagrams of wire temperature at a fixed hydrogen concentration vs. co-reactant concentration reveal multiplicity features which cannot be accounted for just by thermal interaction. The ignited branch was discontinuous at intermediate H2 concentrations and extinction occurred upon increasing the co-reactant concentration. The loci of the observed ignition and extinction points were used to construct a bifurcation map in the concentration plane. The maps show that kinetic inhibition exists between the two reactions in addition to thermal interaction.",

author = "Xiao, {R. R.} and M. Sheintuch and D. Luss",

year = "1986",

doi = "10.1016/0009-2509(86)87125-1",

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T1 - Experimental study of bifurcation diagrams and maps of two parallel interacting catalytic reactions

AU - Xiao, R. R.

AU - Sheintuch, M.

AU - Luss, D.

PY - 1986

Y1 - 1986

N2 - Steady state multiplicity features of systems in which two reactions occur simultaneously may be affected by thermal and kinetic interactions and be qualitatively different from those of a single reaction. This is illustrated by an experimental study of the catalytic co-oxidation of hydrogen with either ammonia, butane or ethylene on a Pt wire. The bifurcation diagrams of wire temperature at a fixed hydrogen concentration vs. co-reactant concentration reveal multiplicity features which cannot be accounted for just by thermal interaction. The ignited branch was discontinuous at intermediate H2 concentrations and extinction occurred upon increasing the co-reactant concentration. The loci of the observed ignition and extinction points were used to construct a bifurcation map in the concentration plane. The maps show that kinetic inhibition exists between the two reactions in addition to thermal interaction.

AB - Steady state multiplicity features of systems in which two reactions occur simultaneously may be affected by thermal and kinetic interactions and be qualitatively different from those of a single reaction. This is illustrated by an experimental study of the catalytic co-oxidation of hydrogen with either ammonia, butane or ethylene on a Pt wire. The bifurcation diagrams of wire temperature at a fixed hydrogen concentration vs. co-reactant concentration reveal multiplicity features which cannot be accounted for just by thermal interaction. The ignited branch was discontinuous at intermediate H2 concentrations and extinction occurred upon increasing the co-reactant concentration. The loci of the observed ignition and extinction points were used to construct a bifurcation map in the concentration plane. The maps show that kinetic inhibition exists between the two reactions in addition to thermal interaction.

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DO - 10.1016/0009-2509(86)87125-1

M3 - 文章

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SN - 0009-2509

VL - 41

SP - 2085

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JO - Chemical Engineering Science

JF - Chemical Engineering Science

IS - 8

ER -

Experimental study of bifurcation diagrams and maps of two parallel interacting catalytic reactions

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