Cyclopolymerization of 1,6-heptadienes catalyzed by iron and cobalt complexes: Synthesis of polymers with trans- or cis-fused 1,2-cyclopentanediyl groups depending on the catalyst

Daisuke Takeuchi; Ryuichi Matsuura; Sehoon Park; Kohtaro Osakada

doi:10.1021/ja0718568

Cyclopolymerization of 1,6-heptadienes catalyzed by iron and cobalt complexes: Synthesis of polymers with trans- or cis-fused 1,2-cyclopentanediyl groups depending on the catalyst

Daisuke Takeuchi, Ryuichi Matsuura, Sehoon Park, Kohtaro Osakada^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

74 Scopus citations

Abstract

The Fe and Co complexes with a bis(imino)pyridine ligand promote the polymerization of 1,6-heptadienes with quantitative cyclization to yield polymers containing five-membered rings. The polymers composed of cis-fused five-membered rings and trans-fused rings are obtained selectively by choosing the catalyst.

Original language	English
Pages (from-to)	7002-7003
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	22
DOIs	https://doi.org/10.1021/ja0718568
State	Published - 6 Jun 2007
Externally published	Yes

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10.1021/ja0718568

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title = "Cyclopolymerization of 1,6-heptadienes catalyzed by iron and cobalt complexes: Synthesis of polymers with trans- or cis-fused 1,2-cyclopentanediyl groups depending on the catalyst",

abstract = "The Fe and Co complexes with a bis(imino)pyridine ligand promote the polymerization of 1,6-heptadienes with quantitative cyclization to yield polymers containing five-membered rings. The polymers composed of cis-fused five-membered rings and trans-fused rings are obtained selectively by choosing the catalyst.",

author = "Daisuke Takeuchi and Ryuichi Matsuura and Sehoon Park and Kohtaro Osakada",

year = "2007",

month = jun,

day = "6",

doi = "10.1021/ja0718568",

language = "英语",

volume = "129",

pages = "7002--7003",

journal = "Journal of the American Chemical Society",

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Cyclopolymerization of 1,6-heptadienes catalyzed by iron and cobalt complexes: Synthesis of polymers with trans- or cis-fused 1,2-cyclopentanediyl groups depending on the catalyst. / Takeuchi, Daisuke; Matsuura, Ryuichi; Park, Sehoon et al.
In: Journal of the American Chemical Society, Vol. 129, No. 22, 06.06.2007, p. 7002-7003.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Cyclopolymerization of 1,6-heptadienes catalyzed by iron and cobalt complexes

T2 - Synthesis of polymers with trans- or cis-fused 1,2-cyclopentanediyl groups depending on the catalyst

AU - Takeuchi, Daisuke

AU - Matsuura, Ryuichi

AU - Park, Sehoon

AU - Osakada, Kohtaro

PY - 2007/6/6

Y1 - 2007/6/6

N2 - The Fe and Co complexes with a bis(imino)pyridine ligand promote the polymerization of 1,6-heptadienes with quantitative cyclization to yield polymers containing five-membered rings. The polymers composed of cis-fused five-membered rings and trans-fused rings are obtained selectively by choosing the catalyst.

AB - The Fe and Co complexes with a bis(imino)pyridine ligand promote the polymerization of 1,6-heptadienes with quantitative cyclization to yield polymers containing five-membered rings. The polymers composed of cis-fused five-membered rings and trans-fused rings are obtained selectively by choosing the catalyst.

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U2 - 10.1021/ja0718568

DO - 10.1021/ja0718568

M3 - 文章

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AN - SCOPUS:34250186758

SN - 0002-7863

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 22

ER -

Cyclopolymerization of 1,6-heptadienes catalyzed by iron and cobalt complexes: Synthesis of polymers with trans- or cis-fused 1,2-cyclopentanediyl groups depending on the catalyst

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