Abstract
Six and seven membered N-heterocyclic iminato ligands (L) are introduced allowing access a new class of Th(iv) complexes of the type Cp∗2Th(L)(CH3). These complexes were studied in the Tishchenko reaction. Stoichiometric reactions together with kinetic and thermodynamic studies permit us to propose a plausible mechanism.
Original language | English |
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Pages (from-to) | 12005-12009 |
Number of pages | 5 |
Journal | Dalton Transactions |
Volume | 46 |
Issue number | 36 |
DOIs | |
State | Published - 2017 |
Externally published | Yes |