TY - JOUR
T1 - The K+Oriented CH3I reaction
T2 - The correlation between reagents' orientation and products' angular distribution
AU - Schechter, I.
AU - Levine, R. D.
N1 - Funding Information:
This work was supported by the US-Israel Binational Science Foundation (BSF), Jerusalem, Israel. The Fritz Haber Research Center is supported by the Mineva Gesellschaft ftir die Forschung, mbH Munich, FRG.
PY - 1988/12/30
Y1 - 1988/12/30
N2 - Kinematic considerations are shown to imply that the steric requirements of the title reaction will be most manifested for backwards reactive scattering, as is observed (Parker et al., Chem. Phys. Letters 86 (1982) 113). The computed dependence of the differential reaction cross section on the orientation of CH3I is progressively weaker as the KI product is scattered into less backward directions, in accord with experiment. A kinematic model with an orientation-dependent barrier to reaction and an impulsive release of the exoergicity is employed.
AB - Kinematic considerations are shown to imply that the steric requirements of the title reaction will be most manifested for backwards reactive scattering, as is observed (Parker et al., Chem. Phys. Letters 86 (1982) 113). The computed dependence of the differential reaction cross section on the orientation of CH3I is progressively weaker as the KI product is scattered into less backward directions, in accord with experiment. A kinematic model with an orientation-dependent barrier to reaction and an impulsive release of the exoergicity is employed.
UR - http://www.scopus.com/inward/record.url?scp=0013638088&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(88)85255-2
DO - 10.1016/0009-2614(88)85255-2
M3 - 文章
AN - SCOPUS:0013638088
SN - 0009-2614
VL - 153
SP - 527
EP - 533
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 6
ER -