Sonochemically prepared high dispersed Ru/TiO 2 mesoporous catalyst for partial oxidation of methane to syngas

Nina Perkas; Ziyi Zhong; Luwei Chen; Michele Besson; Aharon Gedanken

doi:10.1007/s10562-005-6496-4

Sonochemically prepared high dispersed Ru/TiO ₂ mesoporous catalyst for partial oxidation of methane to syngas

Nina Perkas, Ziyi Zhong, Luwei Chen, Michele Besson, Aharon Gedanken^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

71 Scopus citations

Abstract

Highly dispersed Ru nanoparticles on mesoporous TiO ₂ have been synthesized by a one-step ultrasound assisted polyol reduction procedure. The catalysts have been characterized by XRD, TEM and HR-TEM, EDX, BET and TPR methods. It has been demonstrated that the sonochemical method reduces the Ru ⁺³ ions creating a narrow size distribution of metallic nanoparticles deposited on the mesoporous support without damaging its pore structure. The nanoparticles of Ru are highly dispersed and stable because of their incorporation into the mesopores, and the strong metal-support interaction. The catalytic properties of Ru/TiO ₂(MSP) have been tested in the partial oxidation of methane, and high activity and selectivity towards CO and H ₂ have been demonstrated.

Original language	English
Pages (from-to)	9-14
Number of pages	6
Journal	Catalysis Letters
Volume	103
Issue number	1-2
DOIs	https://doi.org/10.1007/s10562-005-6496-4
State	Published - Sep 2005
Externally published	Yes

Keywords

Mesoporous support
Nanoparticles
Partial methane oxidation
Syngas
Ultrasound irradiation

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10.1007/s10562-005-6496-4

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title = "Sonochemically prepared high dispersed Ru/TiO 2 mesoporous catalyst for partial oxidation of methane to syngas",

abstract = "Highly dispersed Ru nanoparticles on mesoporous TiO 2 have been synthesized by a one-step ultrasound assisted polyol reduction procedure. The catalysts have been characterized by XRD, TEM and HR-TEM, EDX, BET and TPR methods. It has been demonstrated that the sonochemical method reduces the Ru +3 ions creating a narrow size distribution of metallic nanoparticles deposited on the mesoporous support without damaging its pore structure. The nanoparticles of Ru are highly dispersed and stable because of their incorporation into the mesopores, and the strong metal-support interaction. The catalytic properties of Ru/TiO 2(MSP) have been tested in the partial oxidation of methane, and high activity and selectivity towards CO and H 2 have been demonstrated.",

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author = "Nina Perkas and Ziyi Zhong and Luwei Chen and Michele Besson and Aharon Gedanken",

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doi = "10.1007/s10562-005-6496-4",

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T1 - Sonochemically prepared high dispersed Ru/TiO 2 mesoporous catalyst for partial oxidation of methane to syngas

AU - Perkas, Nina

AU - Zhong, Ziyi

AU - Chen, Luwei

AU - Besson, Michele

AU - Gedanken, Aharon

PY - 2005/9

Y1 - 2005/9

N2 - Highly dispersed Ru nanoparticles on mesoporous TiO 2 have been synthesized by a one-step ultrasound assisted polyol reduction procedure. The catalysts have been characterized by XRD, TEM and HR-TEM, EDX, BET and TPR methods. It has been demonstrated that the sonochemical method reduces the Ru +3 ions creating a narrow size distribution of metallic nanoparticles deposited on the mesoporous support without damaging its pore structure. The nanoparticles of Ru are highly dispersed and stable because of their incorporation into the mesopores, and the strong metal-support interaction. The catalytic properties of Ru/TiO 2(MSP) have been tested in the partial oxidation of methane, and high activity and selectivity towards CO and H 2 have been demonstrated.

AB - Highly dispersed Ru nanoparticles on mesoporous TiO 2 have been synthesized by a one-step ultrasound assisted polyol reduction procedure. The catalysts have been characterized by XRD, TEM and HR-TEM, EDX, BET and TPR methods. It has been demonstrated that the sonochemical method reduces the Ru +3 ions creating a narrow size distribution of metallic nanoparticles deposited on the mesoporous support without damaging its pore structure. The nanoparticles of Ru are highly dispersed and stable because of their incorporation into the mesopores, and the strong metal-support interaction. The catalytic properties of Ru/TiO 2(MSP) have been tested in the partial oxidation of methane, and high activity and selectivity towards CO and H 2 have been demonstrated.

KW - Mesoporous support

KW - Nanoparticles

KW - Partial methane oxidation

KW - Syngas

KW - Ultrasound irradiation

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DO - 10.1007/s10562-005-6496-4

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JO - Catalysis Letters

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Sonochemically prepared high dispersed Ru/TiO ₂ mesoporous catalyst for partial oxidation of methane to syngas

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Keywords

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