Selective C−O Bond Cleavage of Sugars with Hydrosilanes Catalyzed by Piers’ Borane Generated In Situ

Engineering & Materials Science

• Sugars 100%
• Piers 93%
• Regioselectivity 85%
• Disaccharides 78%
• Monosaccharides 71%
• Catalyst selectivity 60%
• Polyols 59%
• Catalyst activity 51%
• Catalysts 34%
• Carbon 31%

Chemical Compounds

• Borane 90%
• Polyol 86%
• Disaccharide 85%
• Substituent Effect 83%
• Regioselectivity 78%
• Cleavage 56%
• Environment 46%
• Carbon Atom 38%
• Reduction 37%
• Catalyst 34%