Poly(Ionic Liquid)s-in-Salt Electrolytes with Co-coordination-Assisted Lithium-Ion Transport for Safe Batteries

Xiaoen Wang; Fangfang Chen; Gaetan M.A. Girard; Haijin Zhu; Douglas R. MacFarlane; David Mecerreyes; Michel Armand; Patrick C. Howlett; Maria Forsyth

doi:10.1016/j.joule.2019.07.008

Poly(Ionic Liquid)s-in-Salt Electrolytes with Co-coordination-Assisted Lithium-Ion Transport for Safe Batteries

Xiaoen Wang, Fangfang Chen, Gaetan M.A. Girard, Haijin Zhu, Douglas R. MacFarlane, David Mecerreyes, Michel Armand, Patrick C. Howlett, Maria Forsyth^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

105 Scopus citations

Abstract

The properties of polymer hosts and their interactions with lithium salt are critically important for the design of alternative polymer electrolytes for safe lithium battery applications. Herein, we report a poly(ionic liquid) host as a solid electrolyte platform and propose a different coordination mechanism manipulating lithium-ion diffusion compared with traditional polymer systems. Our finding provides a new strategy to develop high-performance polymer electrolytes for next-generation high-energy-density lithium-metal batteries.

Original language	English
Pages (from-to)	2687-2702
Number of pages	16
Journal	Joule
Volume	3
Issue number	11
DOIs	https://doi.org/10.1016/j.joule.2019.07.008
State	Published - 20 Nov 2019
Externally published	Yes

Keywords

Li-ion transport
Li-metal batteries
high energy density
high salt concentration
molecular dynamics
poly(ionic liquid)s (polyILs)
solid polymer electrolytes
solvent free

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10.1016/j.joule.2019.07.008

Cite this

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title = "Poly(Ionic Liquid)s-in-Salt Electrolytes with Co-coordination-Assisted Lithium-Ion Transport for Safe Batteries",

abstract = "The properties of polymer hosts and their interactions with lithium salt are critically important for the design of alternative polymer electrolytes for safe lithium battery applications. Herein, we report a poly(ionic liquid) host as a solid electrolyte platform and propose a different coordination mechanism manipulating lithium-ion diffusion compared with traditional polymer systems. Our finding provides a new strategy to develop high-performance polymer electrolytes for next-generation high-energy-density lithium-metal batteries.",

keywords = "Li-ion transport, Li-metal batteries, high energy density, high salt concentration, molecular dynamics, poly(ionic liquid)s (polyILs), solid polymer electrolytes, solvent free",

author = "Xiaoen Wang and Fangfang Chen and Girard, {Gaetan M.A.} and Haijin Zhu and MacFarlane, {Douglas R.} and David Mecerreyes and Michel Armand and Howlett, {Patrick C.} and Maria Forsyth",

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month = nov,

day = "20",

doi = "10.1016/j.joule.2019.07.008",

language = "英语",

volume = "3",

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TY - JOUR

T1 - Poly(Ionic Liquid)s-in-Salt Electrolytes with Co-coordination-Assisted Lithium-Ion Transport for Safe Batteries

AU - Wang, Xiaoen

AU - Chen, Fangfang

AU - Girard, Gaetan M.A.

AU - Zhu, Haijin

AU - MacFarlane, Douglas R.

AU - Mecerreyes, David

AU - Armand, Michel

AU - Howlett, Patrick C.

AU - Forsyth, Maria

PY - 2019/11/20

Y1 - 2019/11/20

N2 - The properties of polymer hosts and their interactions with lithium salt are critically important for the design of alternative polymer electrolytes for safe lithium battery applications. Herein, we report a poly(ionic liquid) host as a solid electrolyte platform and propose a different coordination mechanism manipulating lithium-ion diffusion compared with traditional polymer systems. Our finding provides a new strategy to develop high-performance polymer electrolytes for next-generation high-energy-density lithium-metal batteries.

AB - The properties of polymer hosts and their interactions with lithium salt are critically important for the design of alternative polymer electrolytes for safe lithium battery applications. Herein, we report a poly(ionic liquid) host as a solid electrolyte platform and propose a different coordination mechanism manipulating lithium-ion diffusion compared with traditional polymer systems. Our finding provides a new strategy to develop high-performance polymer electrolytes for next-generation high-energy-density lithium-metal batteries.

KW - Li-ion transport

KW - Li-metal batteries

KW - high energy density

KW - high salt concentration

KW - molecular dynamics

KW - poly(ionic liquid)s (polyILs)

KW - solid polymer electrolytes

KW - solvent free

UR - http://www.scopus.com/inward/record.url?scp=85074923901&partnerID=8YFLogxK

U2 - 10.1016/j.joule.2019.07.008

DO - 10.1016/j.joule.2019.07.008

M3 - 文章

AN - SCOPUS:85074923901

SN - 2542-4351

VL - 3

SP - 2687

EP - 2702

JO - Joule

JF - Joule

IS - 11

ER -

Poly(Ionic Liquid)s-in-Salt Electrolytes with Co-coordination-Assisted Lithium-Ion Transport for Safe Batteries

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Keywords

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