TY - JOUR
T1 - Polyaniline-cobalt hydroxide hybrid nanostructures and their supercapacitor studies
AU - Shendkar, Janardhan H.
AU - Zate, Manohar
AU - Tehare, Kailas
AU - Jadhav, Vijaykumar V.
AU - Mane, Rajaram S.
AU - Naushad, Mu
AU - Yun, Je Moon
AU - Kim, Kwang Ho
N1 - Publisher Copyright:
© 2016 Elsevier B.V.
PY - 2016/9/1
Y1 - 2016/9/1
N2 - We attempt to demonstrate comprehensive analysis of experimentally obtained adverse supercapacitive performance of cobalt hydroxide (Co(OH)2)-polyaniline (PANI) hybrid nanocomposites (HNs), prepared potentiostatically via electrochemical deposition method, compared to phase pure individual nanostructures. Morphologically amorphous Co(OH)2, PANI and HNs are entirely different from one another. The electrochemical properties of the Co(OH)2, PANI and HNs electrodes have been investigated by cyclic voltammograms, galvanostatic charge-discharge and electrochemical impedance spectroscopy measurements. The specific capacitances of PANI, HNs and Co(OH)2 are found to be 3.06F/g, 215F/g and 868F/g, respectively, at a sweep rate of 10 mV/s in 1.0 M NaOH electrolyte, whereas the stabilities and voltammetric charges, assigned to these electrodes, are 47%, 60% & 55% (after 1000 cycles) and 17.22 mC/cm2, 836.39 mC/cm2 and 1128.73 mC/cm2, respectively. Obtained adverse (inferior) supercapacitive performance values of HNs electrodes have been demonstrated on occurrence of inner and outer charges concept. Our work demonstrates plausible causes for observed smaller supercapacitor performance in hybrid/composite nanostructured electrodes (not a common practice) and useful to researchers working in composite/hybrid symmetric and asymmetric supercapacitor fields.
AB - We attempt to demonstrate comprehensive analysis of experimentally obtained adverse supercapacitive performance of cobalt hydroxide (Co(OH)2)-polyaniline (PANI) hybrid nanocomposites (HNs), prepared potentiostatically via electrochemical deposition method, compared to phase pure individual nanostructures. Morphologically amorphous Co(OH)2, PANI and HNs are entirely different from one another. The electrochemical properties of the Co(OH)2, PANI and HNs electrodes have been investigated by cyclic voltammograms, galvanostatic charge-discharge and electrochemical impedance spectroscopy measurements. The specific capacitances of PANI, HNs and Co(OH)2 are found to be 3.06F/g, 215F/g and 868F/g, respectively, at a sweep rate of 10 mV/s in 1.0 M NaOH electrolyte, whereas the stabilities and voltammetric charges, assigned to these electrodes, are 47%, 60% & 55% (after 1000 cycles) and 17.22 mC/cm2, 836.39 mC/cm2 and 1128.73 mC/cm2, respectively. Obtained adverse (inferior) supercapacitive performance values of HNs electrodes have been demonstrated on occurrence of inner and outer charges concept. Our work demonstrates plausible causes for observed smaller supercapacitor performance in hybrid/composite nanostructured electrodes (not a common practice) and useful to researchers working in composite/hybrid symmetric and asymmetric supercapacitor fields.
KW - Electrochemical deposition
KW - Electrochemical supercapacitor
KW - Nanofibers
KW - Nanoplatelets
KW - Polyaniline
UR - http://www.scopus.com/inward/record.url?scp=84971668226&partnerID=8YFLogxK
U2 - 10.1016/j.matchemphys.2016.05.070
DO - 10.1016/j.matchemphys.2016.05.070
M3 - 文章
AN - SCOPUS:84971668226
SN - 0254-0584
VL - 180
SP - 226
EP - 236
JO - Materials Chemistry and Physics
JF - Materials Chemistry and Physics
ER -