Phase change materials of n-alkane-containing microcapsules: Observation of coexistence of ordered and rotator phases

Dongsheng Fu, Yunlan Su*, Baoquan Xie, Haijin Zhu, Guoming Liu, Dujin Wang

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

36 Scopus citations

Abstract

In the present investigation, the crystallization and phase transition behaviours of normal alkane (n-docosane) in microcapsules with a mean diameter of 3.6 μm were studied by the combination of differential scanning calorimetry (DSC), temperature-dependent X-ray diffraction (XRD) and variable-temperature solid-state nuclear magnetic resonance (VT solid-state 13C NMR). The DSC and VT solid-state 13C NMR results reveal that a surface freezing monolayer is formed prior to the bulk crystallization of the microencapsulated n-docosane. More interestingly, it is confirmed that after the bulk crystallization, the ordered triclinic phase coexists with the rotator phase I (RI) for the microencapsulated n-docosane. We argue that the reduction of the free energy difference between the two phases, resulting from the microencapsulation process, leads to the coexistence of the ordered triclinic and rotator phases of the normal alkanes.

Original languageEnglish
Pages (from-to)2021-2026
Number of pages6
JournalPhysical Chemistry Chemical Physics
Volume13
Issue number6
DOIs
StatePublished - 14 Feb 2011
Externally publishedYes

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