Functionalized α,ω-dienes undergo cyclopolymerization to afford the polymer containing trans-fused five-membered rings. Various dienes including diallyl malonates and diallyl amines are usable for the cyclopolymerization. Copolymerization of dienes with ethylene and α-olefins using Pd complexes produces the copolymer containing five-membered rings. The NMR of poly(l-co-hexene) showed selective insertion mode of the dienes and 1-hexene. The insertion and cyclization of the diene in the copolymerization takes place analogously to those in the homopolymerization.
|Number of pages||2|
|State||Published - 2006|
|Event||55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, Japan|
Duration: 20 Sep 2006 → 22 Sep 2006
|Conference||55th Society of Polymer Science Japan Symposium on Macromolecules|
|Period||20/09/06 → 22/09/06|
- Pd catalysts