Palladium on iron oxide nanoparticles: The morphological effect of the support in glycerol hydrogenolysis

TY - JOUR

T1 - Palladium on iron oxide nanoparticles

T2 - The morphological effect of the support in glycerol hydrogenolysis

AU - Ge, Junwei

AU - Zeng, Ziyan

AU - Liao, Fenglin

AU - Zheng, Weiran

AU - Hong, Xinlin

AU - Tsang, Shik Chi Edman

PY - 2013/8

Y1 - 2013/8

N2 - Palladium supported on different shaped iron oxides has been synthesized and tested in glycerol hydrogenolysis in order to investigate the morphological effect of the support on catalytic performance. The plate-like iron oxide support exhibits a much higher activity due to the presence of more basic sites (oxygen vacancies) on its predominant polar surface. Thus, by tailoring the shape of the crystallized support, we show that bifunctional metal-oxide catalysis at the interface, like in the present example, can be significantly manipulated.

AB - Palladium supported on different shaped iron oxides has been synthesized and tested in glycerol hydrogenolysis in order to investigate the morphological effect of the support on catalytic performance. The plate-like iron oxide support exhibits a much higher activity due to the presence of more basic sites (oxygen vacancies) on its predominant polar surface. Thus, by tailoring the shape of the crystallized support, we show that bifunctional metal-oxide catalysis at the interface, like in the present example, can be significantly manipulated.

UR - http://www.scopus.com/inward/record.url?scp=84884185284&partnerID=8YFLogxK

U2 - 10.1039/c3gc40712h

DO - 10.1039/c3gc40712h

M3 - 文章

AN - SCOPUS:84884185284

SN - 1463-9262

VL - 15

SP - 2064

EP - 2069

JO - Green Chemistry

JF - Green Chemistry

IS - 8

ER -