One-step construction of heterostructured metal-organics@Bi₂O₃ with improved photoinduced charge transfer and enhanced activity in photocatalytic degradation of sulfamethoxazole under solar light irradiation

TY - JOUR

T1 - One-step construction of heterostructured metal-organics@Bi2O3 with improved photoinduced charge transfer and enhanced activity in photocatalytic degradation of sulfamethoxazole under solar light irradiation

AU - Bao, Yueping

AU - Lim, Teik Thye

AU - Goei, Ronn

AU - Zhong, Ziyi

AU - Wang, Rong

AU - Hu, Xiao

N1 - Publisher Copyright: © 2018

PY - 2018/8

Y1 - 2018/8

N2 - A facile one-step assembly method was developed for the preparation of metal-organics @Bi2O3 composites for photocatalysis. Two kinds of metal-organics (Ti-bdc and Cu-btc)@Bi2O3 composites were synthesized via the coordination of btc3−/bdc2− and metal ions (Ti4+/Cu2+) as well as –OH on the surface of Bi2O3. Compared with pure Bi2O3, Ti-bdc@Bi2O3 shows a 1.7 times higher photocatalytic activity in the degradation of sulfamethoxazole (SMX) under a simulated solar irradiation with a cumulative removal of 62% within 60 min. The high photocatalytic activity could be attributed to the high charge separation, enhanced electron transfer as well as the low recombination rate of photo-generated electrons and holes due to the construction of hetero-structures. The stability test showed that Ti-bdc@Bi2O3 is more stable in water than Cu-btc@Bi2O3. Furthermore, through the radical-trapping experiments and main intermediates detection, it is demonstrated that the photo-generated holes as well as the [rad]OH and [rad]O2− formed dominate the photocatalytic decomposition of SMX. These findings demonstrate the potential usage of a facile method to synthesize metal-organics and metal oxides composites, some of which possess high water stability and thus could be employed for water treatment.

AB - A facile one-step assembly method was developed for the preparation of metal-organics @Bi2O3 composites for photocatalysis. Two kinds of metal-organics (Ti-bdc and Cu-btc)@Bi2O3 composites were synthesized via the coordination of btc3−/bdc2− and metal ions (Ti4+/Cu2+) as well as –OH on the surface of Bi2O3. Compared with pure Bi2O3, Ti-bdc@Bi2O3 shows a 1.7 times higher photocatalytic activity in the degradation of sulfamethoxazole (SMX) under a simulated solar irradiation with a cumulative removal of 62% within 60 min. The high photocatalytic activity could be attributed to the high charge separation, enhanced electron transfer as well as the low recombination rate of photo-generated electrons and holes due to the construction of hetero-structures. The stability test showed that Ti-bdc@Bi2O3 is more stable in water than Cu-btc@Bi2O3. Furthermore, through the radical-trapping experiments and main intermediates detection, it is demonstrated that the photo-generated holes as well as the [rad]OH and [rad]O2− formed dominate the photocatalytic decomposition of SMX. These findings demonstrate the potential usage of a facile method to synthesize metal-organics and metal oxides composites, some of which possess high water stability and thus could be employed for water treatment.

KW - Charge transfer

KW - Composite

KW - Metal-organics

KW - Photocatalytic degradation

KW - Sulfamethoxazole

UR - http://www.scopus.com/inward/record.url?scp=85047466467&partnerID=8YFLogxK

U2 - 10.1016/j.chemosphere.2018.04.031

DO - 10.1016/j.chemosphere.2018.04.031

M3 - 文章

C2 - 29704847

AN - SCOPUS:85047466467

SN - 0045-6535

VL - 205

SP - 396

EP - 403

JO - Chemosphere

JF - Chemosphere

ER -