Intermolecular hydroamination of terminal alkynes catalyzed by organoactinide complexes. Scope and mechanistic studies

Chemical Compounds

• Hydroamination 77%
• Alkyne 51%
• Primary Aliphatic Amine 31%
• Amine 28%
• Imine 26%
• Regioselectivity 14%
• Brook Silaketone Rearrangement 11%
• Thorium 8%
• Enamine 8%
• Actinoid Atom 8%
• Chemoselectivity 7%
• Catalyst 6%
• Oligomer 5%
• Isomerization 5%
• Toluene 5%
• Single Crystal X-Ray Diffraction 5%
• Benzene 5%
• Catalysis 4%

Physics & Astronomy

• alkynes 100%
• amines 70%
• imines 34%
• catalysts 11%
• thorium 7%
• kinetics 7%
• isomerization 6%
• oligomers 6%
• toluene 6%
• uranium 6%
• benzene 5%
• insertion 5%
• cycles 4%
• products 3%
• single crystals 3%
• diffraction 3%
• x rays 2%