Abstract
Cationic silane complex 2, catalyzes the hydrosilylation of epoxides and cyclic ethers to give the silyl-protected alcohols, regioselectively. A mechanistic study shows that the epoxide undergoes isomerization to the ketone, followed by hydrosilylation.
Original language | English |
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Pages (from-to) | 3643-3645 |
Number of pages | 3 |
Journal | Chemical Communications |
Volume | 47 |
Issue number | 12 |
DOIs | |
State | Published - 8 Mar 2011 |
Externally published | Yes |