Formation of Elastomeric Polypropylene Promoted by Racemic Acetylacetonate Group 4 Complexes

Michal Shmulinson; Mercedes Galan-Fereres; Anatoly Lisovskii; Elza Nelkenbaum; Rafi Semiat; Moris S. Eisen

doi:10.1021/om9908985

Formation of Elastomeric Polypropylene Promoted by Racemic Acetylacetonate Group 4 Complexes

Michal Shmulinson, Mercedes Galan-Fereres, Anatoly Lisovskii, Elza Nelkenbaum, Rafi Semiat, Moris S. Eisen^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Summary: Treatment of racemic bis(acetylacetonato) group 4 complexes with MAO yields cationic complexes acting as active catalysts for the polymerization of propylene under high monomeric concentrations. By the appropriate choice of metal and solvent the properties of the polymer products can be tailored, allowing the formation of either elastomer to highly isotactic polypropylene.

Original language	English
Pages (from-to)	1208-1210
Number of pages	3
Journal	Organometallics
Volume	19
Issue number	7
DOIs	https://doi.org/10.1021/om9908985
State	Published - 3 Apr 2000
Externally published	Yes

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title = "Formation of Elastomeric Polypropylene Promoted by Racemic Acetylacetonate Group 4 Complexes",

abstract = "Summary: Treatment of racemic bis(acetylacetonato) group 4 complexes with MAO yields cationic complexes acting as active catalysts for the polymerization of propylene under high monomeric concentrations. By the appropriate choice of metal and solvent the properties of the polymer products can be tailored, allowing the formation of either elastomer to highly isotactic polypropylene.",

author = "Michal Shmulinson and Mercedes Galan-Fereres and Anatoly Lisovskii and Elza Nelkenbaum and Rafi Semiat and Eisen, {Moris S.}",

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doi = "10.1021/om9908985",

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AU - Shmulinson, Michal

AU - Galan-Fereres, Mercedes

AU - Lisovskii, Anatoly

AU - Nelkenbaum, Elza

AU - Semiat, Rafi

AU - Eisen, Moris S.

PY - 2000/4/3

Y1 - 2000/4/3

N2 - Summary: Treatment of racemic bis(acetylacetonato) group 4 complexes with MAO yields cationic complexes acting as active catalysts for the polymerization of propylene under high monomeric concentrations. By the appropriate choice of metal and solvent the properties of the polymer products can be tailored, allowing the formation of either elastomer to highly isotactic polypropylene.

AB - Summary: Treatment of racemic bis(acetylacetonato) group 4 complexes with MAO yields cationic complexes acting as active catalysts for the polymerization of propylene under high monomeric concentrations. By the appropriate choice of metal and solvent the properties of the polymer products can be tailored, allowing the formation of either elastomer to highly isotactic polypropylene.

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U2 - 10.1021/om9908985

DO - 10.1021/om9908985

M3 - 文章

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VL - 19

SP - 1208

EP - 1210

JO - Organometallics

JF - Organometallics

IS - 7

ER -

Formation of Elastomeric Polypropylene Promoted by Racemic Acetylacetonate Group 4 Complexes

Abstract

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