Efficient gas sensitivity in mixed bismuth ferrite micro (cubes) and nano (plates) structures

Shivaji D. Waghmare; Vijaykumar V. Jadhav; Shaym K. Gore; Seog Joon Yoon; Swapnil B. Ambade; B. J. Lokhande; Rajaram S. Mane; Sung Hwan Han

doi:10.1016/j.materresbull.2012.08.078

Efficient gas sensitivity in mixed bismuth ferrite micro (cubes) and nano (plates) structures

Shivaji D. Waghmare, Vijaykumar V. Jadhav, Shaym K. Gore, Seog Joon Yoon, Swapnil B. Ambade, B. J. Lokhande, Rajaram S. Mane^*, Sung Hwan Han

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

Mixed micro (cubes) and nano (plates) structures of bismuth ferrite (BFO) have been synthesized by a simple and cost-effective wet-chemical method. Structural, morphological and phase confirmation characteristics are measured using X-ray diffraction, field-emission scanning electron microscopy (FE-SEM) and energy dispersive X-ray analysis techniques. The digital FE-SEM photo-images of BFO sample confirmed an incubation of discrete micro-cubes into thin and regularly placed large number of nano-plates. The bismuth ferrite, with mixed structures, films show considerable performance when used in liquefied petroleum (LPG), carbon dioxide (CO ₂) and ammonium (NH ₃) gas sensors application. Different chemical entities in LPG have made it more efficient with higher sensitivity, recovery and response times compared to CO ₂ and NH ₃ gases. Furthermore, effect of palladium surface treatment on the gas sensitivity and the charge transfer resistances of BFO mixed structures is investigated and reported.

Original language	English
Pages (from-to)	4169-4173
Number of pages	5
Journal	Materials Research Bulletin
Volume	47
Issue number	12
DOIs	https://doi.org/10.1016/j.materresbull.2012.08.078
State	Published - Dec 2012
Externally published	Yes

Keywords

A. Oxides
B. Chemical synthesis
C. Impedance spectroscopy
C. Surface properties

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10.1016/j.materresbull.2012.08.078

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@article{b563f726bfba4bcb8b41301e3ce0dff1,

title = "Efficient gas sensitivity in mixed bismuth ferrite micro (cubes) and nano (plates) structures",

abstract = "Mixed micro (cubes) and nano (plates) structures of bismuth ferrite (BFO) have been synthesized by a simple and cost-effective wet-chemical method. Structural, morphological and phase confirmation characteristics are measured using X-ray diffraction, field-emission scanning electron microscopy (FE-SEM) and energy dispersive X-ray analysis techniques. The digital FE-SEM photo-images of BFO sample confirmed an incubation of discrete micro-cubes into thin and regularly placed large number of nano-plates. The bismuth ferrite, with mixed structures, films show considerable performance when used in liquefied petroleum (LPG), carbon dioxide (CO 2) and ammonium (NH 3) gas sensors application. Different chemical entities in LPG have made it more efficient with higher sensitivity, recovery and response times compared to CO 2 and NH 3 gases. Furthermore, effect of palladium surface treatment on the gas sensitivity and the charge transfer resistances of BFO mixed structures is investigated and reported.",

keywords = "A. Oxides, B. Chemical synthesis, C. Impedance spectroscopy, C. Surface properties",

author = "Waghmare, {Shivaji D.} and Jadhav, {Vijaykumar V.} and Gore, {Shaym K.} and Yoon, {Seog Joon} and Ambade, {Swapnil B.} and Lokhande, {B. J.} and Mane, {Rajaram S.} and Han, {Sung Hwan}",

note = "Funding Information: This work was supported by a Korea Science and Engineering Foundation (KOSEF) grant funded by the Ministry of Education, Science and Technology (MEST) of Korea for the Center for Next Generation Dye-sensitized Solar Cells (No. 2009-0063373 ).",

year = "2012",

month = dec,

doi = "10.1016/j.materresbull.2012.08.078",

language = "英语",

volume = "47",

pages = "4169--4173",

journal = "Materials Research Bulletin",

issn = "0025-5408",

publisher = "Elsevier Ltd.",

number = "12",

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TY - JOUR

T1 - Efficient gas sensitivity in mixed bismuth ferrite micro (cubes) and nano (plates) structures

AU - Waghmare, Shivaji D.

AU - Jadhav, Vijaykumar V.

AU - Gore, Shaym K.

AU - Yoon, Seog Joon

AU - Ambade, Swapnil B.

AU - Lokhande, B. J.

AU - Mane, Rajaram S.

AU - Han, Sung Hwan

N1 - Funding Information: This work was supported by a Korea Science and Engineering Foundation (KOSEF) grant funded by the Ministry of Education, Science and Technology (MEST) of Korea for the Center for Next Generation Dye-sensitized Solar Cells (No. 2009-0063373 ).

PY - 2012/12

Y1 - 2012/12

N2 - Mixed micro (cubes) and nano (plates) structures of bismuth ferrite (BFO) have been synthesized by a simple and cost-effective wet-chemical method. Structural, morphological and phase confirmation characteristics are measured using X-ray diffraction, field-emission scanning electron microscopy (FE-SEM) and energy dispersive X-ray analysis techniques. The digital FE-SEM photo-images of BFO sample confirmed an incubation of discrete micro-cubes into thin and regularly placed large number of nano-plates. The bismuth ferrite, with mixed structures, films show considerable performance when used in liquefied petroleum (LPG), carbon dioxide (CO 2) and ammonium (NH 3) gas sensors application. Different chemical entities in LPG have made it more efficient with higher sensitivity, recovery and response times compared to CO 2 and NH 3 gases. Furthermore, effect of palladium surface treatment on the gas sensitivity and the charge transfer resistances of BFO mixed structures is investigated and reported.

AB - Mixed micro (cubes) and nano (plates) structures of bismuth ferrite (BFO) have been synthesized by a simple and cost-effective wet-chemical method. Structural, morphological and phase confirmation characteristics are measured using X-ray diffraction, field-emission scanning electron microscopy (FE-SEM) and energy dispersive X-ray analysis techniques. The digital FE-SEM photo-images of BFO sample confirmed an incubation of discrete micro-cubes into thin and regularly placed large number of nano-plates. The bismuth ferrite, with mixed structures, films show considerable performance when used in liquefied petroleum (LPG), carbon dioxide (CO 2) and ammonium (NH 3) gas sensors application. Different chemical entities in LPG have made it more efficient with higher sensitivity, recovery and response times compared to CO 2 and NH 3 gases. Furthermore, effect of palladium surface treatment on the gas sensitivity and the charge transfer resistances of BFO mixed structures is investigated and reported.

KW - A. Oxides

KW - B. Chemical synthesis

KW - C. Impedance spectroscopy

KW - C. Surface properties

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U2 - 10.1016/j.materresbull.2012.08.078

DO - 10.1016/j.materresbull.2012.08.078

M3 - 文章

AN - SCOPUS:84868201175

SN - 0025-5408

VL - 47

SP - 4169

EP - 4173

JO - Materials Research Bulletin

JF - Materials Research Bulletin

IS - 12

ER -

Efficient gas sensitivity in mixed bismuth ferrite micro (cubes) and nano (plates) structures

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