Analysis and Modeling of Multiplicity Features. 1. Nonisothermal Experiments

TY - JOUR

T1 - Analysis and Modeling of Multiplicity Features. 1. Nonisothermal Experiments

AU - Harold, Michael P.

AU - Sheintuch, Moshe

AU - Luss, Dan

PY - 1987/4/1

Y1 - 1987/4/1

N2 - A methodology is presented for elucidating the functional features of the isothermal rate expression from an analysis of the multiplicity features of nonisothermal experiments. The necessary kinetic features are predicted from an analysis of either a bifurcation diagram (dependence of surface temperature on bulk temperature or concentration) or a bifurcation map (dependence of ignition and extinction points on two operating conditions). The methodology is illustrated by the analysis of several published nonisothermal bifurcation diagrams to gain information about the functional form of an isothermal rate expression, which can describe the observed data.

AB - A methodology is presented for elucidating the functional features of the isothermal rate expression from an analysis of the multiplicity features of nonisothermal experiments. The necessary kinetic features are predicted from an analysis of either a bifurcation diagram (dependence of surface temperature on bulk temperature or concentration) or a bifurcation map (dependence of ignition and extinction points on two operating conditions). The methodology is illustrated by the analysis of several published nonisothermal bifurcation diagrams to gain information about the functional form of an isothermal rate expression, which can describe the observed data.

UR - http://www.scopus.com/inward/record.url?scp=0023330022&partnerID=8YFLogxK

U2 - 10.1021/ie00064a029

DO - 10.1021/ie00064a029

M3 - 文章

AN - SCOPUS:0023330022

SN - 0888-5885

VL - 26

SP - 786

EP - 794

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 4

ER -