Amino-functionalized mesoporous silica based polyethersulfone-polyvinylpyrrolidone composite membrane for elevated temperature fuel cells

J. Zhang; S. F. Lu; H. J. Zhu; K. F. Chen; J. Liu; Y. Xiang; M. Forsyth; S. P. Jianga

doi:10.1149/07514.0581ecst

Amino-functionalized mesoporous silica based polyethersulfone-polyvinylpyrrolidone composite membrane for elevated temperature fuel cells

J. Zhang, S. F. Lu, H. J. Zhu, K. F. Chen, J. Liu, Y. Xiang, M. Forsyth, S. P. Jianga

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Inorganic-organic nanostructured hybrid membranes based on polyethersulfone (PES)-polyvinylpyrrolidone (PVP) were prepared with mesoporous silica materials. All the hybrid membranes showed the similar phosphoric acid (PA) uptake. However, the proton conductivity of the PA-PES-PVP membrane was significantly increased after the addition of the inorganic fillers, especially for the amino-functionalized hollow mesoporous silica (NH2-HMS). The cell performance test also confirmed the superiority of the PES-PVP membranes with the inorganic fillers. The highest peak power density at 180 oC reached up to 480 mW cm-2 for the NH2-HMS based composite membrane fuel cell, which is 92.7 % higher than that of the PA-PES-PVP membrane fuel cell at the identical condition. The outstanding performance of the inorganic-organic hybrid membranes might be due to the facilitated proton transportation in the ordered mesoporous channels, and the great water retention of the inorganic fillers.

Original language	English
Title of host publication	Polymer Electrolyte Fuel Cells 16, PEFC 16
Editors	D. J. Jones, H. Uchida, H. A. Gasteiger, K. Swider-Lyons, F. N. Buchi, P. N. Pintauro, B. S. Pivovar, K. E. Ayers, K. A. Perry, P. Shirvanian, A. Z. Weber, V. K. Ramani, P. Strasser, R. A. Mantz, K. Shinohara, S. Mitsushima, C. Coutanceau, J. M. Fenton, T. J. Schmidt, T. F. Fuller, S. R. Narayanan, Y. T. Kim, L. Zhuang, S. G. Sun
Publisher	Electrochemical Society Inc.
Pages	581-588
Number of pages	8
Edition	14
ISBN (Electronic)	9781607687313, 9781607687672, 9781607687689, 9781607687696, 9781607687702, 9781607687719, 9781607687726, 9781607687733, 9781607687740, 9781607687757, 9781607687771, 9781607687788, 9781607687795, 9781607687801, 9781607687818, 9781607687825, 9781607687832, 9781607687849, 9781607687856, 9781607687863, 9781607687887, 9781607687894, 9781607687900, 9781607687917, 9781607687924, 9781607687931, 9781607687948, 9781607687955, 9781607687962, 9781607687979, 9781607687986, 9781607687993, 9781607688006, 9781607688013, 9781607688020, 9781607688037
DOIs	https://doi.org/10.1149/07514.0581ecst
State	Published - 2016
Externally published	Yes
Event	Symposium on Polymer Electrolyte Fuel Cells 16, PEFC 2016 - PRiME 2016/230th ECS Meeting - Honolulu, United States Duration: 2 Oct 2016 → 7 Oct 2016

Publication series

Name	ECS Transactions
Number	14
Volume	75
ISSN (Print)	1938-6737
ISSN (Electronic)	1938-5862

Conference

Conference	Symposium on Polymer Electrolyte Fuel Cells 16, PEFC 2016 - PRiME 2016/230th ECS Meeting
Country/Territory	United States
City	Honolulu
Period	2/10/16 → 7/10/16

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10.1149/07514.0581ecst

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Zhang, J., Lu, S. F., Zhu, H. J., Chen, K. F., Liu, J., Xiang, Y., Forsyth, M., & Jianga, S. P. (2016). Amino-functionalized mesoporous silica based polyethersulfone-polyvinylpyrrolidone composite membrane for elevated temperature fuel cells. In D. J. Jones, H. Uchida, H. A. Gasteiger, K. Swider-Lyons, F. N. Buchi, P. N. Pintauro, B. S. Pivovar, K. E. Ayers, K. A. Perry, P. Shirvanian, A. Z. Weber, V. K. Ramani, P. Strasser, R. A. Mantz, K. Shinohara, S. Mitsushima, C. Coutanceau, J. M. Fenton, T. J. Schmidt, T. F. Fuller, S. R. Narayanan, Y. T. Kim, L. Zhuang, ... S. G. Sun (Eds.), Polymer Electrolyte Fuel Cells 16, PEFC 16 (14 ed., pp. 581-588). (ECS Transactions; Vol. 75, No. 14). Electrochemical Society Inc.. https://doi.org/10.1149/07514.0581ecst

Zhang, J. ; Lu, S. F. ; Zhu, H. J. et al. / Amino-functionalized mesoporous silica based polyethersulfone-polyvinylpyrrolidone composite membrane for elevated temperature fuel cells. Polymer Electrolyte Fuel Cells 16, PEFC 16. editor / D. J. Jones ; H. Uchida ; H. A. Gasteiger ; K. Swider-Lyons ; F. N. Buchi ; P. N. Pintauro ; B. S. Pivovar ; K. E. Ayers ; K. A. Perry ; P. Shirvanian ; A. Z. Weber ; V. K. Ramani ; P. Strasser ; R. A. Mantz ; K. Shinohara ; S. Mitsushima ; C. Coutanceau ; J. M. Fenton ; T. J. Schmidt ; T. F. Fuller ; S. R. Narayanan ; Y. T. Kim ; L. Zhuang ; S. G. Sun. 14. ed. Electrochemical Society Inc., 2016. pp. 581-588 (ECS Transactions; 14).

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title = "Amino-functionalized mesoporous silica based polyethersulfone-polyvinylpyrrolidone composite membrane for elevated temperature fuel cells",

abstract = "Inorganic-organic nanostructured hybrid membranes based on polyethersulfone (PES)-polyvinylpyrrolidone (PVP) were prepared with mesoporous silica materials. All the hybrid membranes showed the similar phosphoric acid (PA) uptake. However, the proton conductivity of the PA-PES-PVP membrane was significantly increased after the addition of the inorganic fillers, especially for the amino-functionalized hollow mesoporous silica (NH2-HMS). The cell performance test also confirmed the superiority of the PES-PVP membranes with the inorganic fillers. The highest peak power density at 180 oC reached up to 480 mW cm-2 for the NH2-HMS based composite membrane fuel cell, which is 92.7 % higher than that of the PA-PES-PVP membrane fuel cell at the identical condition. The outstanding performance of the inorganic-organic hybrid membranes might be due to the facilitated proton transportation in the ordered mesoporous channels, and the great water retention of the inorganic fillers.",

author = "J. Zhang and Lu, {S. F.} and Zhu, {H. J.} and Chen, {K. F.} and J. Liu and Y. Xiang and M. Forsyth and Jianga, {S. P.}",

note = "Publisher Copyright: {\textcopyright} 2016 The Electrochemical Society.; null ; Conference date: 02-10-2016 Through 07-10-2016",

year = "2016",

doi = "10.1149/07514.0581ecst",

language = "英语",

series = "ECS Transactions",

publisher = "Electrochemical Society Inc.",

number = "14",

pages = "581--588",

editor = "Jones, {D. J.} and H. Uchida and Gasteiger, {H. A.} and K. Swider-Lyons and Buchi, {F. N.} and Pintauro, {P. N.} and Pivovar, {B. S.} and Ayers, {K. E.} and Perry, {K. A.} and P. Shirvanian and Weber, {A. Z.} and Ramani, {V. K.} and P. Strasser and Mantz, {R. A.} and K. Shinohara and S. Mitsushima and C. Coutanceau and Fenton, {J. M.} and Schmidt, {T. J.} and Fuller, {T. F.} and Narayanan, {S. R.} and Kim, {Y. T.} and L. Zhuang and Sun, {S. G.}",

booktitle = "Polymer Electrolyte Fuel Cells 16, PEFC 16",

edition = "14",

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Zhang, J, Lu, SF, Zhu, HJ, Chen, KF, Liu, J, Xiang, Y, Forsyth, M & Jianga, SP 2016, Amino-functionalized mesoporous silica based polyethersulfone-polyvinylpyrrolidone composite membrane for elevated temperature fuel cells. in DJ Jones, H Uchida, HA Gasteiger, K Swider-Lyons, FN Buchi, PN Pintauro, BS Pivovar, KE Ayers, KA Perry, P Shirvanian, AZ Weber, VK Ramani, P Strasser, RA Mantz, K Shinohara, S Mitsushima, C Coutanceau, JM Fenton, TJ Schmidt, TF Fuller, SR Narayanan, YT Kim, L Zhuang & SG Sun (eds), Polymer Electrolyte Fuel Cells 16, PEFC 16. 14 edn, ECS Transactions, no. 14, vol. 75, Electrochemical Society Inc., pp. 581-588, Symposium on Polymer Electrolyte Fuel Cells 16, PEFC 2016 - PRiME 2016/230th ECS Meeting, Honolulu, United States, 2/10/16. https://doi.org/10.1149/07514.0581ecst

Amino-functionalized mesoporous silica based polyethersulfone-polyvinylpyrrolidone composite membrane for elevated temperature fuel cells. / Zhang, J.; Lu, S. F.; Zhu, H. J. et al.

Polymer Electrolyte Fuel Cells 16, PEFC 16. ed. / D. J. Jones; H. Uchida; H. A. Gasteiger; K. Swider-Lyons; F. N. Buchi; P. N. Pintauro; B. S. Pivovar; K. E. Ayers; K. A. Perry; P. Shirvanian; A. Z. Weber; V. K. Ramani; P. Strasser; R. A. Mantz; K. Shinohara; S. Mitsushima; C. Coutanceau; J. M. Fenton; T. J. Schmidt; T. F. Fuller; S. R. Narayanan; Y. T. Kim; L. Zhuang; S. G. Sun. 14. ed. Electrochemical Society Inc., 2016. p. 581-588 (ECS Transactions; Vol. 75, No. 14).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Amino-functionalized mesoporous silica based polyethersulfone-polyvinylpyrrolidone composite membrane for elevated temperature fuel cells

AU - Zhang, J.

AU - Lu, S. F.

AU - Zhu, H. J.

AU - Chen, K. F.

AU - Liu, J.

AU - Xiang, Y.

AU - Forsyth, M.

AU - Jianga, S. P.

PY - 2016

Y1 - 2016

N2 - Inorganic-organic nanostructured hybrid membranes based on polyethersulfone (PES)-polyvinylpyrrolidone (PVP) were prepared with mesoporous silica materials. All the hybrid membranes showed the similar phosphoric acid (PA) uptake. However, the proton conductivity of the PA-PES-PVP membrane was significantly increased after the addition of the inorganic fillers, especially for the amino-functionalized hollow mesoporous silica (NH2-HMS). The cell performance test also confirmed the superiority of the PES-PVP membranes with the inorganic fillers. The highest peak power density at 180 oC reached up to 480 mW cm-2 for the NH2-HMS based composite membrane fuel cell, which is 92.7 % higher than that of the PA-PES-PVP membrane fuel cell at the identical condition. The outstanding performance of the inorganic-organic hybrid membranes might be due to the facilitated proton transportation in the ordered mesoporous channels, and the great water retention of the inorganic fillers.

AB - Inorganic-organic nanostructured hybrid membranes based on polyethersulfone (PES)-polyvinylpyrrolidone (PVP) were prepared with mesoporous silica materials. All the hybrid membranes showed the similar phosphoric acid (PA) uptake. However, the proton conductivity of the PA-PES-PVP membrane was significantly increased after the addition of the inorganic fillers, especially for the amino-functionalized hollow mesoporous silica (NH2-HMS). The cell performance test also confirmed the superiority of the PES-PVP membranes with the inorganic fillers. The highest peak power density at 180 oC reached up to 480 mW cm-2 for the NH2-HMS based composite membrane fuel cell, which is 92.7 % higher than that of the PA-PES-PVP membrane fuel cell at the identical condition. The outstanding performance of the inorganic-organic hybrid membranes might be due to the facilitated proton transportation in the ordered mesoporous channels, and the great water retention of the inorganic fillers.

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U2 - 10.1149/07514.0581ecst

DO - 10.1149/07514.0581ecst

M3 - 会议稿件

AN - SCOPUS:84991702452

T3 - ECS Transactions

SP - 581

EP - 588

BT - Polymer Electrolyte Fuel Cells 16, PEFC 16

A2 - Jones, D. J.

A2 - Uchida, H.

A2 - Gasteiger, H. A.

A2 - Swider-Lyons, K.

A2 - Buchi, F. N.

A2 - Pintauro, P. N.

A2 - Pivovar, B. S.

A2 - Ayers, K. E.

A2 - Perry, K. A.

A2 - Shirvanian, P.

A2 - Weber, A. Z.

A2 - Ramani, V. K.

A2 - Strasser, P.

A2 - Mantz, R. A.

A2 - Shinohara, K.

A2 - Mitsushima, S.

A2 - Coutanceau, C.

A2 - Fenton, J. M.

A2 - Schmidt, T. J.

A2 - Fuller, T. F.

A2 - Narayanan, S. R.

A2 - Kim, Y. T.

A2 - Zhuang, L.

A2 - Sun, S. G.

PB - Electrochemical Society Inc.

Y2 - 2 October 2016 through 7 October 2016

ER -

Zhang J, Lu SF, Zhu HJ, Chen KF, Liu J, Xiang Y et al. Amino-functionalized mesoporous silica based polyethersulfone-polyvinylpyrrolidone composite membrane for elevated temperature fuel cells. In Jones DJ, Uchida H, Gasteiger HA, Swider-Lyons K, Buchi FN, Pintauro PN, Pivovar BS, Ayers KE, Perry KA, Shirvanian P, Weber AZ, Ramani VK, Strasser P, Mantz RA, Shinohara K, Mitsushima S, Coutanceau C, Fenton JM, Schmidt TJ, Fuller TF, Narayanan SR, Kim YT, Zhuang L, Sun SG, editors, Polymer Electrolyte Fuel Cells 16, PEFC 16. 14 ed. Electrochemical Society Inc. 2016. p. 581-588. (ECS Transactions; 14). doi: 10.1149/07514.0581ecst

Amino-functionalized mesoporous silica based polyethersulfone-polyvinylpyrrolidone composite membrane for elevated temperature fuel cells

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