@inbook{f9f4e811a5a74e77866f7df109f46b0c,
title = "Phillips Cr/silica catalyst for ethylene polymerization",
abstract = "The Phillips Cr/silica catalyst, discovered by Hogan and Banks at the Phillips Petroleum Company in the early 1950s, is one of the most important industrial catalysts for polyethylene production. In contrast to its great commercial success during the past half-century, academic progress regarding a basic understanding of the nature of the active sites and polymerization mechanisms is lagging far behind. During the last decade, increasing research efforts have been performed on the Phillips catalyst through various approaches, including spectroscopic methods, polymerization kinetics, heterogeneous model catalysts, homogeneous model catalysts, and molecular modeling. Much deeper mechanistic understanding, together with successive catalyst innovations through modifications of the Phillips catalyst, has been achieved.",
keywords = "Ethylene polymerization mechanisms, Heterogeneous model catalysts, Homogeneous model catalysts, Molecular modeling, Phillips Cr/silica catalyst, Polyethylene, Polymerization kinetics",
author = "Ruihua Cheng and Zhen Liu and Lei Zhong and Xuelian He and Pengyuan Qiu and Minoru Terano and Eisen, {Moris S.} and Scott, {Susannah L.} and Boping Liu",
note = "Funding Information: We are gratefully thankful for the financial support by the National Natural Science Foundation of China (No. 21104019 and 21274040), the National High Technology Research and Development Program 863 (2012AA040306), and the Shanghai Science and Technology Commission (Key Project for Basic Research 10JC1403700). This work is also financially supported by the Fundamental Research Funds for the Central Universities, Research Program of Introducing Talents of Discipline of University (B08021).",
year = "2013",
doi = "10.1007/12_2013_222",
language = "英语",
isbn = "9783642408076",
series = "Advances in Polymer Science",
publisher = "Springer New York LLC",
pages = "135--202",
booktitle = "Polyolefins",
}