P-H functionalised phosphinoalkoxides as ligands: Synthesis and catalytic properties of [Cp2Zr(Me)(cyclo-1-O-2-PH(Tipp)-C6H10)] (Tipp=2,4,6-Pri3C6H2), [Cp2Zr(Me)(cyclo-1-O-2-PH(Tipp){Mo(CO)5}-C 6H10)] and Cp2Zr(BH4) [Cp2Zr(BH4).

Thomas Koch; Steffen Blaurock; Evamarie Hey-Hawkins; Mercedes Galan-Fereres; Dorit Plat; Moris S. Eisen

doi:10.1016/S0022-328X(99)00597-5

P-H functionalised phosphinoalkoxides as ligands: Synthesis and catalytic properties of [Cp₂Zr(Me)(cyclo-1-O-2-PH(Tipp)-C₆H₁₀)] (Tipp=2,4,6-Prⁱ₃C₆H₂), [Cp₂Zr(Me)(cyclo-1-O-2-PH(Tipp){Mo(CO)₅}-C ₆H₁₀)] and Cp₂Zr(BH₄) [Cp₂Zr(BH₄).

Thomas Koch^*, Steffen Blaurock, Evamarie Hey-Hawkins, Mercedes Galan-Fereres, Dorit Plat, Moris S. Eisen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The P-H functionalised phosphinoalcohol 1-PH(Tipp)-2-OH-cyclo-C₆H₁₀ (Tipp=2,4,6-Prⁱ₃C₆H₂) reacts with [Cp₂ZrMe₂] with elimination of methane to give exclusively the mono-substituted product [Cp₂Zr(Me)(cyclo-1-O-2-PH(Tipp)-C₆H₁₀)] (1), even at elevated temperature. 1 reacts with [Mo(CO)₅(NMe₃)] to give the heterodinuclear complex [Cp₂Zr(Me)(cyclo-1-O-2-PH(Tipp){Mo(CO)₅}-C ₆H₁₀)] (2). The borane adduct [Cp₂Zr(BH₄)(cyclo-1-O-2-PH(Mes)(BH₃)-C ₆H₁₀)] (3, Mes=2,4,6-Me₃C₆H₂) was obtained from [Cp₂Zr(BH₄)₂] and 1-PH(Mes)-2-OH-cyclo-C₆H₁₀ in boiling hexane. 1-3 were characterised spectroscopically (¹H, ¹³C, ³¹P, ¹¹B (for 3), MS, and IR). A crystal structure determination of the R_C,R_C,R_P/S_C,S_C,S _P isomer of 1 was obtained. The complexes 1-3 were studied in the catalytic polymerisation of ethylene and propylene by activating them with methylalumoxane (MAO) as cocatalyst.

Original language	English
Pages (from-to)	126-133
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	595
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(99)00597-5
State	Published - 31 Jan 2000
Externally published	Yes

Keywords

Borane adduct
Heterodinuclear molybdenum phosphine complex
P-H functionalised phosphinoalkoxide
Zirconocene complex

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Koch, T., Blaurock, S., Hey-Hawkins, E., Galan-Fereres, M., Plat, D., & Eisen, M. S. (2000). P-H functionalised phosphinoalkoxides as ligands: Synthesis and catalytic properties of [Cp₂Zr(Me)(cyclo-1-O-2-PH(Tipp)-C₆H₁₀)] (Tipp=2,4,6-Prⁱ₃C₆H₂), [Cp₂Zr(Me)(cyclo-1-O-2-PH(Tipp){Mo(CO)₅}-C ₆H₁₀)] and Cp₂Zr(BH₄) [Cp₂Zr(BH₄). Journal of Organometallic Chemistry, 595(1), 126-133. https://doi.org/10.1016/S0022-328X(99)00597-5

Koch, Thomas ; Blaurock, Steffen ; Hey-Hawkins, Evamarie et al. / P-H functionalised phosphinoalkoxides as ligands : Synthesis and catalytic properties of [Cp₂Zr(Me)(cyclo-1-O-2-PH(Tipp)-C₆H₁₀)] (Tipp=2,4,6-Prⁱ₃C₆H₂), [Cp₂Zr(Me)(cyclo-1-O-2-PH(Tipp){Mo(CO)₅}-C ₆H₁₀)] and Cp₂Zr(BH₄) [Cp₂Zr(BH₄). In: Journal of Organometallic Chemistry. 2000 ; Vol. 595, No. 1. pp. 126-133.

@article{aa9b8b4d506c4ecc86ca2811cb37f1da,

title = "P-H functionalised phosphinoalkoxides as ligands: Synthesis and catalytic properties of [Cp2Zr(Me)(cyclo-1-O-2-PH(Tipp)-C6H10)] (Tipp=2,4,6-Pri3C6H2), [Cp2Zr(Me)(cyclo-1-O-2-PH(Tipp){Mo(CO)5}-C 6H10)] and Cp2Zr(BH4) [Cp2Zr(BH4).",

abstract = "The P-H functionalised phosphinoalcohol 1-PH(Tipp)-2-OH-cyclo-C6H10 (Tipp=2,4,6-Pri3C6H2) reacts with [Cp2ZrMe2] with elimination of methane to give exclusively the mono-substituted product [Cp2Zr(Me)(cyclo-1-O-2-PH(Tipp)-C6H10)] (1), even at elevated temperature. 1 reacts with [Mo(CO)5(NMe3)] to give the heterodinuclear complex [Cp2Zr(Me)(cyclo-1-O-2-PH(Tipp){Mo(CO)5}-C 6H10)] (2). The borane adduct [Cp2Zr(BH4)(cyclo-1-O-2-PH(Mes)(BH3)-C 6H10)] (3, Mes=2,4,6-Me3C6H2) was obtained from [Cp2Zr(BH4)2] and 1-PH(Mes)-2-OH-cyclo-C6H10 in boiling hexane. 1-3 were characterised spectroscopically (1H, 13C, 31P, 11B (for 3), MS, and IR). A crystal structure determination of the RC,RC,RP/SC,SC,S P isomer of 1 was obtained. The complexes 1-3 were studied in the catalytic polymerisation of ethylene and propylene by activating them with methylalumoxane (MAO) as cocatalyst.",

keywords = "Borane adduct, Heterodinuclear molybdenum phosphine complex, P-H functionalised phosphinoalkoxide, Zirconocene complex",

author = "Thomas Koch and Steffen Blaurock and Evamarie Hey-Hawkins and Mercedes Galan-Fereres and Dorit Plat and Eisen, {Moris S.}",

note = "Funding Information: We gratefully acknowledge financial support from the German–Israeli Foundation grant no. I-142/95, the Fonds der Chemischen Industrie and the Fund for the Promotion of Research at the Technion. S.B. acknowledges support by the S{\"a}chsisches Ministerium f{\"u}r Wissenschaft und Kunst (Landesgraduiertenstipendium).",

year = "2000",

month = jan,

day = "31",

doi = "10.1016/S0022-328X(99)00597-5",

language = "英语",

volume = "595",

pages = "126--133",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "1",

}

Koch, T, Blaurock, S, Hey-Hawkins, E, Galan-Fereres, M, Plat, D & Eisen, MS 2000, 'P-H functionalised phosphinoalkoxides as ligands: Synthesis and catalytic properties of [Cp₂Zr(Me)(cyclo-1-O-2-PH(Tipp)-C₆H₁₀)] (Tipp=2,4,6-Prⁱ₃C₆H₂), [Cp₂Zr(Me)(cyclo-1-O-2-PH(Tipp){Mo(CO)₅}-C ₆H₁₀)] and Cp₂Zr(BH₄) [Cp₂Zr(BH₄).', Journal of Organometallic Chemistry, vol. 595, no. 1, pp. 126-133. https://doi.org/10.1016/S0022-328X(99)00597-5

P-H functionalised phosphinoalkoxides as ligands: Synthesis and catalytic properties of [Cp₂Zr(Me)(cyclo-1-O-2-PH(Tipp)-C₆H₁₀)] (Tipp=2,4,6-Prⁱ₃C₆H₂), [Cp₂Zr(Me)(cyclo-1-O-2-PH(Tipp){Mo(CO)₅}-C ₆H₁₀)] and Cp₂Zr(BH₄) [Cp₂Zr(BH₄). / Koch, Thomas; Blaurock, Steffen; Hey-Hawkins, Evamarie et al.
In: Journal of Organometallic Chemistry, Vol. 595, No. 1, 31.01.2000, p. 126-133.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - P-H functionalised phosphinoalkoxides as ligands

T2 - Synthesis and catalytic properties of [Cp2Zr(Me)(cyclo-1-O-2-PH(Tipp)-C6H10)] (Tipp=2,4,6-Pri3C6H2), [Cp2Zr(Me)(cyclo-1-O-2-PH(Tipp){Mo(CO)5}-C 6H10)] and Cp2Zr(BH4) [Cp2Zr(BH4).

AU - Koch, Thomas

AU - Blaurock, Steffen

AU - Hey-Hawkins, Evamarie

AU - Galan-Fereres, Mercedes

AU - Plat, Dorit

AU - Eisen, Moris S.

N1 - Funding Information: We gratefully acknowledge financial support from the German–Israeli Foundation grant no. I-142/95, the Fonds der Chemischen Industrie and the Fund for the Promotion of Research at the Technion. S.B. acknowledges support by the Sächsisches Ministerium für Wissenschaft und Kunst (Landesgraduiertenstipendium).

PY - 2000/1/31

Y1 - 2000/1/31

N2 - The P-H functionalised phosphinoalcohol 1-PH(Tipp)-2-OH-cyclo-C6H10 (Tipp=2,4,6-Pri3C6H2) reacts with [Cp2ZrMe2] with elimination of methane to give exclusively the mono-substituted product [Cp2Zr(Me)(cyclo-1-O-2-PH(Tipp)-C6H10)] (1), even at elevated temperature. 1 reacts with [Mo(CO)5(NMe3)] to give the heterodinuclear complex [Cp2Zr(Me)(cyclo-1-O-2-PH(Tipp){Mo(CO)5}-C 6H10)] (2). The borane adduct [Cp2Zr(BH4)(cyclo-1-O-2-PH(Mes)(BH3)-C 6H10)] (3, Mes=2,4,6-Me3C6H2) was obtained from [Cp2Zr(BH4)2] and 1-PH(Mes)-2-OH-cyclo-C6H10 in boiling hexane. 1-3 were characterised spectroscopically (1H, 13C, 31P, 11B (for 3), MS, and IR). A crystal structure determination of the RC,RC,RP/SC,SC,S P isomer of 1 was obtained. The complexes 1-3 were studied in the catalytic polymerisation of ethylene and propylene by activating them with methylalumoxane (MAO) as cocatalyst.

AB - The P-H functionalised phosphinoalcohol 1-PH(Tipp)-2-OH-cyclo-C6H10 (Tipp=2,4,6-Pri3C6H2) reacts with [Cp2ZrMe2] with elimination of methane to give exclusively the mono-substituted product [Cp2Zr(Me)(cyclo-1-O-2-PH(Tipp)-C6H10)] (1), even at elevated temperature. 1 reacts with [Mo(CO)5(NMe3)] to give the heterodinuclear complex [Cp2Zr(Me)(cyclo-1-O-2-PH(Tipp){Mo(CO)5}-C 6H10)] (2). The borane adduct [Cp2Zr(BH4)(cyclo-1-O-2-PH(Mes)(BH3)-C 6H10)] (3, Mes=2,4,6-Me3C6H2) was obtained from [Cp2Zr(BH4)2] and 1-PH(Mes)-2-OH-cyclo-C6H10 in boiling hexane. 1-3 were characterised spectroscopically (1H, 13C, 31P, 11B (for 3), MS, and IR). A crystal structure determination of the RC,RC,RP/SC,SC,S P isomer of 1 was obtained. The complexes 1-3 were studied in the catalytic polymerisation of ethylene and propylene by activating them with methylalumoxane (MAO) as cocatalyst.

KW - Borane adduct

KW - Heterodinuclear molybdenum phosphine complex

KW - P-H functionalised phosphinoalkoxide

KW - Zirconocene complex

UR - http://www.scopus.com/inward/record.url?scp=0000935974&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(99)00597-5

DO - 10.1016/S0022-328X(99)00597-5

M3 - 文章

AN - SCOPUS:0000935974

SN - 0022-328X

VL - 595

SP - 126

EP - 133

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Koch T, Blaurock S, Hey-Hawkins E, Galan-Fereres M, Plat D, Eisen MS. P-H functionalised phosphinoalkoxides as ligands: Synthesis and catalytic properties of [Cp₂Zr(Me)(cyclo-1-O-2-PH(Tipp)-C₆H₁₀)] (Tipp=2,4,6-Prⁱ₃C₆H₂), [Cp₂Zr(Me)(cyclo-1-O-2-PH(Tipp){Mo(CO)₅}-C ₆H₁₀)] and Cp₂Zr(BH₄) [Cp₂Zr(BH₄). Journal of Organometallic Chemistry. 2000 Jan 31;595(1):126-133. doi: 10.1016/S0022-328X(99)00597-5