Organoactinides promote the Tishchenko reaction: The myth of inactive actinide-alkoxo complexes

Tamer Andrea, Eyal Barnea, Moris S. Eisen*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

54 Scopus citations

Abstract

For many decades, compounds containing oxygen atoms were excluded from the actinide-catalysis field because of the high oxophilic nature of these complexes. Pursuing the conceptual question about the potential activity of actinide-oxo bonds we were surprised to find that the coupling of aromatic aldehydes catalyzed by Cp*2ThMe2 and Th(NEtMe)4 via thorium-alkoxide intermediates takes place in high yields to produce the corresponding esters. In this paper we present our breakthrough results including comprehensive mechanistic, deuterium labeling, kinetic, and thermodynamic studies. A plausible mechanism is presented taking into account as well the thermochemistry of the process.

Original languageEnglish
Pages (from-to)2454-2455
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number8
DOIs
StatePublished - 27 Feb 2008
Externally publishedYes

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