Metallocene organoactinide complexes

Manab Sharma, Moris S. Eisen

Research output: Chapter in Book/Report/Conference proceedingChapterpeer-review

28 Scopus citations

Abstract

During the last decade, the chemistry of d0/fn actinides has flourished reaching a high level of sophistication. Compared to the early or late transition-metal complexes and lanthanides, the actinides sometimes exhibit parallel but mostly complementary activities for similar organic processes, and sometimes even challenge the activities of the transition metals. A rapid increase in the numbers of reports in the Cambridge database also reflects their current importance. In view of the above, in this particular review we have provided an overview and updated information about the preparation and properties of the major classes of actinide complexes containing different cyclopentadienyl ligands and having the oxidation states (+3 and +4).

Original languageEnglish
Title of host publicationOrganometallic and Coordination Chemistry of the Actinides
Pages1-85
Number of pages85
DOIs
StatePublished - 2008
Externally publishedYes

Publication series

NameStructure and Bonding
Volume127
ISSN (Print)0081-5993
ISSN (Electronic)1616-8550

Keywords

  • Metallocene complexes
  • Organoactinides
  • Sterically induced reduction (SIR)

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