Investigation of the siliceous hydrogel phase formation in glass-ionomer cement paste

Chee Wah Loy, Andrew E. Whitten, Liliana de Campo, Dominique Appadoo, Norhazlin Zainuddin, Khamirul Amin Matori, Christine Rehm, Anna Sokolova, Chunhai Wang, Qingbo Xia, Thomas A. Whittle, Siegbert Schmid*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Scopus citations


The microstructure evolution of a complex glass-ionomer cement (GIC) paste over the first 72 h of the cement setting reaction was investigated by small-angle neutron scattering (SANS) and infrared spectroscopy. GIC is a biocompatible material which is clinically used for dental fillings. In this study, GIC pastes were prepared, following the ISO9917-1:2007 cement preparation method, from medical grade poly(acrylic acid), SiO2–Al2O3–P2O5–CaO–CaF2-based fluoroaluminosilicate glass and H2O/D2O solvent. During the setting reaction, polyacrylic acid attacks the fluoroaluminosilicate glass particles to form a siliceous hydrogel phase, glass core and hydrated polyacrylate matrix. The formation of the siliceous hydrogel structure and cross-linking of polyacrylate chains play important roles to harden the GIC. Infrared spectroscopy was used to identify the formation of the hydrogel phase and cross-linkage in GIC paste. In addition this paper reports SANS measurements for GIC pastes at different contrast conditions (H2O:D2O ratio) from the Bilby instrument at the Australian Centre for Neutron Scattering, ANSTO, Australia. The SANS data provide microstructure information for the hydrogel phase in GIC paste over the length scale of 10–5000 Å.

Original languageEnglish
Pages (from-to)287-290
Number of pages4
JournalPhysica B: Condensed Matter
StatePublished - 15 Dec 2018


  • Fluoroaluminosilicate glass
  • Glass-ionomer cement
  • Infrared spectroscopy
  • Setting reaction
  • Small angle neutron scattering

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