Hydrosilylation of epoxides catalyzed by a cationic η1-silane iridium(III) complex

Sehoon Park; Maurice Brookhart

doi:10.1039/c0cc05714b

Hydrosilylation of epoxides catalyzed by a cationic η¹-silane iridium(III) complex

Sehoon Park, Maurice Brookhart^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

Cationic silane complex 2, catalyzes the hydrosilylation of epoxides and cyclic ethers to give the silyl-protected alcohols, regioselectively. A mechanistic study shows that the epoxide undergoes isomerization to the ketone, followed by hydrosilylation.

Original language	English
Pages (from-to)	3643-3645
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	12
DOIs	https://doi.org/10.1039/c0cc05714b
State	Published - 8 Mar 2011
Externally published	Yes

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title = "Hydrosilylation of epoxides catalyzed by a cationic η1-silane iridium(III) complex",

abstract = "Cationic silane complex 2, catalyzes the hydrosilylation of epoxides and cyclic ethers to give the silyl-protected alcohols, regioselectively. A mechanistic study shows that the epoxide undergoes isomerization to the ketone, followed by hydrosilylation.",

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AU - Brookhart, Maurice

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N2 - Cationic silane complex 2, catalyzes the hydrosilylation of epoxides and cyclic ethers to give the silyl-protected alcohols, regioselectively. A mechanistic study shows that the epoxide undergoes isomerization to the ketone, followed by hydrosilylation.

AB - Cationic silane complex 2, catalyzes the hydrosilylation of epoxides and cyclic ethers to give the silyl-protected alcohols, regioselectively. A mechanistic study shows that the epoxide undergoes isomerization to the ketone, followed by hydrosilylation.

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U2 - 10.1039/c0cc05714b

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Hydrosilylation of epoxides catalyzed by a cationic η¹-silane iridium(III) complex

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