Design of organometallic group iv heteroallylic complexes and their catalytic properties for polymerizations and olefin centered transformations

Elena Smolensky, Moris S. Eisen*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

34 Scopus citations

Abstract

The use of metallocenes in many stoichiometric and catalytic processes has been the impetus for the development of new organometallic complexes, especially those containing early transition metals. The formation of coordinative unsaturated complexes using allylic, benzamidinate and aminopyridine families is presented. The synthesis and structural parameters of the new complexes, their activation and use in the polymerization of α-olefins and dienes, in the dehydrogenative coupling of silanes and in the hydroamination reactions comprise the objectives of this review.

Original languageEnglish
Pages (from-to)5623-5650
Number of pages28
JournalDalton Transactions
Issue number48
DOIs
StatePublished - 2007
Externally publishedYes

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