Design of organometallic group iv heteroallylic complexes and their catalytic properties for polymerizations and olefin centered transformations

Elena Smolensky; Moris S. Eisen

doi:10.1039/b707983b

Design of organometallic group iv heteroallylic complexes and their catalytic properties for polymerizations and olefin centered transformations

Elena Smolensky, Moris S. Eisen^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The use of metallocenes in many stoichiometric and catalytic processes has been the impetus for the development of new organometallic complexes, especially those containing early transition metals. The formation of coordinative unsaturated complexes using allylic, benzamidinate and aminopyridine families is presented. The synthesis and structural parameters of the new complexes, their activation and use in the polymerization of α-olefins and dienes, in the dehydrogenative coupling of silanes and in the hydroamination reactions comprise the objectives of this review.

Original language	English
Pages (from-to)	5623-5650
Number of pages	28
Journal	Dalton Transactions
Issue number	48
DOIs	https://doi.org/10.1039/b707983b
State	Published - 2007
Externally published	Yes

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AB - The use of metallocenes in many stoichiometric and catalytic processes has been the impetus for the development of new organometallic complexes, especially those containing early transition metals. The formation of coordinative unsaturated complexes using allylic, benzamidinate and aminopyridine families is presented. The synthesis and structural parameters of the new complexes, their activation and use in the polymerization of α-olefins and dienes, in the dehydrogenative coupling of silanes and in the hydroamination reactions comprise the objectives of this review.

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DO - 10.1039/b707983b

M3 - 文章

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Design of organometallic group iv heteroallylic complexes and their catalytic properties for polymerizations and olefin centered transformations

Abstract

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