TY - JOUR
T1 - Catalytic activity of some homogeneous and silica-bound dirhodium complexes having one bridging thiolato and one bridging chloro ligand
AU - Eisen, Moris
AU - Blum, Jochanan
AU - Schumann, Herbert
AU - Jurgis, Stanislaw
N1 - Funding Information:
We are grateful to the Deutsche Forschungsgemeinschaft (DFG) and the exchange program between the Technical University of Berlin and the Hebrew University of Jerusalem for financial support of this study.
PY - 1985/8/1
Y1 - 1985/8/1
N2 - Several μ-alkylthiolato- and μ-arylthiolato-μ-chloro-dicarbonylbis(tri-t-butylphosphine) dirhodium complexes, Rh2(CO)2(P[C(CH3)3]3)2(μ-Cl)(μ-SR) 3 - 8, were shown to be effective catalysts for hydrogenation, hydroformylation and isomerization of olefins. Silica-attached versions of these complexes, in which the sulfur was linked to the support by a (CH2)nSiO3 (n = 2, 3) bridge, could be recycled for use in further runs. Both the homogeneous and the heterogenized catalysts were shown to retain the dinuclear structure during and after the catalytic processes.
AB - Several μ-alkylthiolato- and μ-arylthiolato-μ-chloro-dicarbonylbis(tri-t-butylphosphine) dirhodium complexes, Rh2(CO)2(P[C(CH3)3]3)2(μ-Cl)(μ-SR) 3 - 8, were shown to be effective catalysts for hydrogenation, hydroformylation and isomerization of olefins. Silica-attached versions of these complexes, in which the sulfur was linked to the support by a (CH2)nSiO3 (n = 2, 3) bridge, could be recycled for use in further runs. Both the homogeneous and the heterogenized catalysts were shown to retain the dinuclear structure during and after the catalytic processes.
UR - http://www.scopus.com/inward/record.url?scp=0022112253&partnerID=8YFLogxK
U2 - 10.1016/0304-5102(85)85114-2
DO - 10.1016/0304-5102(85)85114-2
M3 - 文章
AN - SCOPUS:0022112253
SN - 0304-5102
VL - 31
SP - 317
EP - 326
JO - Journal of Molecular Catalysis
JF - Journal of Molecular Catalysis
IS - 3
ER -