Adhesion-Shielding based synthesis of interfacially active magnetic Janus nanoparticles

Fan Yang; Xiao He; Wen Tan; Gang Liu; Tingting Yi; Qingye Lu; Xiaoting Wei; Hanjie Xie; Qiurong Long; Gui Chao Wang; Chuanfei Guo; Erica Pensini; Zhouguang Lu; Qingxia Liu; Zhenghe Xu

doi:10.1016/j.jcis.2021.08.202

Adhesion-Shielding based synthesis of interfacially active magnetic Janus nanoparticles

Fan Yang, Xiao He, Wen Tan, Gang Liu, Tingting Yi, Qingye Lu, Xiaoting Wei, Hanjie Xie, Qiurong Long, Gui Chao Wang, Chuanfei Guo, Erica Pensini, Zhouguang Lu, Qingxia Liu^*, Zhenghe Xu

^*Corresponding author for this work

Chemical Engineering

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Hypothesis: A unique adhesion-shielding (AS)-based method could be used to manufacture magnetic Janus nanoparticles (IM-JNPs) of promising interfacial activities, asymmetric surface wettability, and great performance on deoiling from oily wastewater under the external magnetic field. Experiments: The IM-JNPs were characterized using scanning electron microscope (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and Fourier-transform infrared spectroscopy (FTIR). The interfacial properties of IM-JNPs were investigated by the measurements of interfacial pressure-area isotherms (π-A), oil–water interfacial tension, and the related crumpling ratio. The Langmuir-Blodgett (L-B) technique was used to determine the asymmetric surface wettability of the IM-JNPs. The performance and recyclability of IM-JNPs for treating oily wastewater were also investigated. Findings: Using the proposed AS-based method, 17.9 g IM-JNPs were synthesized at a time and exhibited excellent interfacial properties, as indicated by decreasing oil–water interfacial tension from 38 to 27 mN/m. The crumpling behavior of the oil droplet further demonstrated the irreversible deposition of IM-JNPs at the oil droplet surfaces. The L-B technique and water contact angle measurement confirmed the asymmetric surface wettability of the IM-JNPs. The IM-JNPs were applied to successful removal of > 90% emulsified oil droplets from the household-produced oily wastewater under the external magnetic field while realizing facile recyclability and regeneration.

Original language	English
Pages (from-to)	1741-1753
Number of pages	13
Journal	Journal of Colloid and Interface Science
Volume	607
DOIs	https://doi.org/10.1016/j.jcis.2021.08.202
State	Published - Feb 2022

Keywords

Adhesion-shielding
Magnetic Janus nanoparticle
Oily wastewater treatment
Scalable synthesis
Starch powder

Access to Document

10.1016/j.jcis.2021.08.202

Cite this

@article{527b3f77243842968d5d0271e2a60a61,

title = "Adhesion-Shielding based synthesis of interfacially active magnetic Janus nanoparticles",

abstract = "Hypothesis: A unique adhesion-shielding (AS)-based method could be used to manufacture magnetic Janus nanoparticles (IM-JNPs) of promising interfacial activities, asymmetric surface wettability, and great performance on deoiling from oily wastewater under the external magnetic field. Experiments: The IM-JNPs were characterized using scanning electron microscope (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and Fourier-transform infrared spectroscopy (FTIR). The interfacial properties of IM-JNPs were investigated by the measurements of interfacial pressure-area isotherms (π-A), oil–water interfacial tension, and the related crumpling ratio. The Langmuir-Blodgett (L-B) technique was used to determine the asymmetric surface wettability of the IM-JNPs. The performance and recyclability of IM-JNPs for treating oily wastewater were also investigated. Findings: Using the proposed AS-based method, 17.9 g IM-JNPs were synthesized at a time and exhibited excellent interfacial properties, as indicated by decreasing oil–water interfacial tension from 38 to 27 mN/m. The crumpling behavior of the oil droplet further demonstrated the irreversible deposition of IM-JNPs at the oil droplet surfaces. The L-B technique and water contact angle measurement confirmed the asymmetric surface wettability of the IM-JNPs. The IM-JNPs were applied to successful removal of > 90% emulsified oil droplets from the household-produced oily wastewater under the external magnetic field while realizing facile recyclability and regeneration.",

keywords = "Adhesion-shielding, Magnetic Janus nanoparticle, Oily wastewater treatment, Scalable synthesis, Starch powder",

author = "Fan Yang and Xiao He and Wen Tan and Gang Liu and Tingting Yi and Qingye Lu and Xiaoting Wei and Hanjie Xie and Qiurong Long and Wang, {Gui Chao} and Chuanfei Guo and Erica Pensini and Zhouguang Lu and Qingxia Liu and Zhenghe Xu",

note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Inc.",

year = "2022",

month = feb,

doi = "10.1016/j.jcis.2021.08.202",

language = "英语",

volume = "607",

pages = "1741--1753",

journal = "Journal of Colloid and Interface Science",

issn = "0021-9797",

publisher = "Academic Press Inc.",

}

TY - JOUR

T1 - Adhesion-Shielding based synthesis of interfacially active magnetic Janus nanoparticles

AU - Yang, Fan

AU - He, Xiao

AU - Tan, Wen

AU - Liu, Gang

AU - Yi, Tingting

AU - Lu, Qingye

AU - Wei, Xiaoting

AU - Xie, Hanjie

AU - Long, Qiurong

AU - Wang, Gui Chao

AU - Guo, Chuanfei

AU - Pensini, Erica

AU - Lu, Zhouguang

AU - Liu, Qingxia

AU - Xu, Zhenghe

PY - 2022/2

Y1 - 2022/2

N2 - Hypothesis: A unique adhesion-shielding (AS)-based method could be used to manufacture magnetic Janus nanoparticles (IM-JNPs) of promising interfacial activities, asymmetric surface wettability, and great performance on deoiling from oily wastewater under the external magnetic field. Experiments: The IM-JNPs were characterized using scanning electron microscope (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and Fourier-transform infrared spectroscopy (FTIR). The interfacial properties of IM-JNPs were investigated by the measurements of interfacial pressure-area isotherms (π-A), oil–water interfacial tension, and the related crumpling ratio. The Langmuir-Blodgett (L-B) technique was used to determine the asymmetric surface wettability of the IM-JNPs. The performance and recyclability of IM-JNPs for treating oily wastewater were also investigated. Findings: Using the proposed AS-based method, 17.9 g IM-JNPs were synthesized at a time and exhibited excellent interfacial properties, as indicated by decreasing oil–water interfacial tension from 38 to 27 mN/m. The crumpling behavior of the oil droplet further demonstrated the irreversible deposition of IM-JNPs at the oil droplet surfaces. The L-B technique and water contact angle measurement confirmed the asymmetric surface wettability of the IM-JNPs. The IM-JNPs were applied to successful removal of > 90% emulsified oil droplets from the household-produced oily wastewater under the external magnetic field while realizing facile recyclability and regeneration.

AB - Hypothesis: A unique adhesion-shielding (AS)-based method could be used to manufacture magnetic Janus nanoparticles (IM-JNPs) of promising interfacial activities, asymmetric surface wettability, and great performance on deoiling from oily wastewater under the external magnetic field. Experiments: The IM-JNPs were characterized using scanning electron microscope (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and Fourier-transform infrared spectroscopy (FTIR). The interfacial properties of IM-JNPs were investigated by the measurements of interfacial pressure-area isotherms (π-A), oil–water interfacial tension, and the related crumpling ratio. The Langmuir-Blodgett (L-B) technique was used to determine the asymmetric surface wettability of the IM-JNPs. The performance and recyclability of IM-JNPs for treating oily wastewater were also investigated. Findings: Using the proposed AS-based method, 17.9 g IM-JNPs were synthesized at a time and exhibited excellent interfacial properties, as indicated by decreasing oil–water interfacial tension from 38 to 27 mN/m. The crumpling behavior of the oil droplet further demonstrated the irreversible deposition of IM-JNPs at the oil droplet surfaces. The L-B technique and water contact angle measurement confirmed the asymmetric surface wettability of the IM-JNPs. The IM-JNPs were applied to successful removal of > 90% emulsified oil droplets from the household-produced oily wastewater under the external magnetic field while realizing facile recyclability and regeneration.

KW - Adhesion-shielding

KW - Magnetic Janus nanoparticle

KW - Oily wastewater treatment

KW - Scalable synthesis

KW - Starch powder

UR - http://www.scopus.com/inward/record.url?scp=85115969590&partnerID=8YFLogxK

U2 - 10.1016/j.jcis.2021.08.202

DO - 10.1016/j.jcis.2021.08.202

M3 - 文章

C2 - 34598031

AN - SCOPUS:85115969590

SN - 0021-9797

VL - 607

SP - 1741

EP - 1753

JO - Journal of Colloid and Interface Science

JF - Journal of Colloid and Interface Science

ER -

Adhesion-Shielding based synthesis of interfacially active magnetic Janus nanoparticles

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this