Wet hydrodechlorination of p-chlorophenol using Pd supported on an activated carbon cloth

Yu Shindler; Yu Matatov-Meytal; M. Sheintuch

doi:10.1021/ie001019d

Wet hydrodechlorination of p-chlorophenol using Pd supported on an activated carbon cloth

Yu Shindler, Yu Matatov-Meytal, M. Sheintuch^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

75 Scopus citations

Abstract

The use of activated carbon cloths as supports for Pd catalyst has been investigated in a hydrodechlorination process. Using p-chlorophenol (CP) as a model compound, the influence of the catalyst preparation procedure and Pd content have been studied at 30-85°C, showing good activity and selectivity. Kinetic analysis of these diffusion-independent results showed the reaction to be first-order with respect to each reactant concentration (CP and hydrogen). Analysis of diffusion and reaction shows that diffusion resistance will be significant in granules larger than 100 μm. Several simulations of adsorption, diffusion, and reaction are presented showing the effect of pellet size, of hydrogen pressure, and of adsorbent loading.

Original language	English
Pages (from-to)	3301-3308
Number of pages	8
Journal	Industrial and Engineering Chemistry Research
Volume	40
Issue number	15
DOIs	https://doi.org/10.1021/ie001019d
State	Published - 15 Jul 2001
Externally published	Yes

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title = "Wet hydrodechlorination of p-chlorophenol using Pd supported on an activated carbon cloth",

abstract = "The use of activated carbon cloths as supports for Pd catalyst has been investigated in a hydrodechlorination process. Using p-chlorophenol (CP) as a model compound, the influence of the catalyst preparation procedure and Pd content have been studied at 30-85°C, showing good activity and selectivity. Kinetic analysis of these diffusion-independent results showed the reaction to be first-order with respect to each reactant concentration (CP and hydrogen). Analysis of diffusion and reaction shows that diffusion resistance will be significant in granules larger than 100 μm. Several simulations of adsorption, diffusion, and reaction are presented showing the effect of pellet size, of hydrogen pressure, and of adsorbent loading.",

author = "Yu Shindler and Yu Matatov-Meytal and M. Sheintuch",

year = "2001",

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AU - Shindler, Yu

AU - Matatov-Meytal, Yu

AU - Sheintuch, M.

PY - 2001/7/15

Y1 - 2001/7/15

N2 - The use of activated carbon cloths as supports for Pd catalyst has been investigated in a hydrodechlorination process. Using p-chlorophenol (CP) as a model compound, the influence of the catalyst preparation procedure and Pd content have been studied at 30-85°C, showing good activity and selectivity. Kinetic analysis of these diffusion-independent results showed the reaction to be first-order with respect to each reactant concentration (CP and hydrogen). Analysis of diffusion and reaction shows that diffusion resistance will be significant in granules larger than 100 μm. Several simulations of adsorption, diffusion, and reaction are presented showing the effect of pellet size, of hydrogen pressure, and of adsorbent loading.

AB - The use of activated carbon cloths as supports for Pd catalyst has been investigated in a hydrodechlorination process. Using p-chlorophenol (CP) as a model compound, the influence of the catalyst preparation procedure and Pd content have been studied at 30-85°C, showing good activity and selectivity. Kinetic analysis of these diffusion-independent results showed the reaction to be first-order with respect to each reactant concentration (CP and hydrogen). Analysis of diffusion and reaction shows that diffusion resistance will be significant in granules larger than 100 μm. Several simulations of adsorption, diffusion, and reaction are presented showing the effect of pellet size, of hydrogen pressure, and of adsorbent loading.

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U2 - 10.1021/ie001019d

DO - 10.1021/ie001019d

M3 - 文章

AN - SCOPUS:0035878090

SN - 0888-5885

VL - 40

SP - 3301

EP - 3308

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 15

ER -

Wet hydrodechlorination of p-chlorophenol using Pd supported on an activated carbon cloth

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