TY - JOUR
T1 - State-of-the-art catechol porphyrin COF catalyst for chemical fixation of carbon dioxide
T2 - Via cyclic carbonates and oxazolidinones
AU - Saptal, Vitthal
AU - Shinde, Digambar Balaji
AU - Banerjee, Rahul
AU - Bhanage, Bhalchandra M.
N1 - Publisher Copyright:
© 2016 The Royal Society of Chemistry.
PY - 2016
Y1 - 2016
N2 - A highly porous, crystalline catechol porphyrin COF was synthesized and applied as an organocatalyst for the chemical fixation of carbon dioxide to synthesize value-added chemicals such as cyclic carbonates and oxazolidinones under solvent-free and transition-metal-free conditions. The high surface area and the functionalities of the COF catalyst act synergistically to activate the starting material. The 2,3-DhaTph shows excellent activity towards cyclic carbonates at the atmospheric pressure of carbon dioxide. Additionally, this catalytic system is recyclable in nature and provides a higher turnover number than previously reported organocatalysts.
AB - A highly porous, crystalline catechol porphyrin COF was synthesized and applied as an organocatalyst for the chemical fixation of carbon dioxide to synthesize value-added chemicals such as cyclic carbonates and oxazolidinones under solvent-free and transition-metal-free conditions. The high surface area and the functionalities of the COF catalyst act synergistically to activate the starting material. The 2,3-DhaTph shows excellent activity towards cyclic carbonates at the atmospheric pressure of carbon dioxide. Additionally, this catalytic system is recyclable in nature and provides a higher turnover number than previously reported organocatalysts.
UR - http://www.scopus.com/inward/record.url?scp=84979895791&partnerID=8YFLogxK
U2 - 10.1039/c6cy00362a
DO - 10.1039/c6cy00362a
M3 - 文章
AN - SCOPUS:84979895791
SN - 2044-4753
VL - 6
SP - 6152
EP - 6158
JO - Catalysis Science and Technology
JF - Catalysis Science and Technology
IS - 15
ER -