Protic organic ionic plastic crystals based on a difunctional cation and the triflate anion: A new solid-state proton conductor

Jun Rao; R. Vijayaraghavan; Fangfang Chen; Haijin Zhu; Patrick C. Howlett; Douglas R. Macfarlane; Maria Forsyth

doi:10.1039/c6cc07154f

Protic organic ionic plastic crystals based on a difunctional cation and the triflate anion: A new solid-state proton conductor

Jun Rao, R. Vijayaraghavan, Fangfang Chen, Haijin Zhu^*, Patrick C. Howlett, Douglas R. Macfarlane, Maria Forsyth

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Two protic organic ionic plastic crystalline materials based on the mono- and di-protonated cations of N,N-dimethylethylenediamine, (DMEDA) and the triflate anion have been studied. The symmetrical di-protonated cation salt shows 54 °C higher melting point and 24-fold higher conductivity at room temperature as compared to the mono-protonated cation salt, making it a promising candidate for a solid-state proton conductor. The conductivity of this salt was further enhanced by acid doping.

Original language	English
Pages (from-to)	14097-14100
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	98
DOIs	https://doi.org/10.1039/c6cc07154f
State	Published - 2016
Externally published	Yes

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title = "Protic organic ionic plastic crystals based on a difunctional cation and the triflate anion: A new solid-state proton conductor",

abstract = "Two protic organic ionic plastic crystalline materials based on the mono- and di-protonated cations of N,N-dimethylethylenediamine, (DMEDA) and the triflate anion have been studied. The symmetrical di-protonated cation salt shows 54 °C higher melting point and 24-fold higher conductivity at room temperature as compared to the mono-protonated cation salt, making it a promising candidate for a solid-state proton conductor. The conductivity of this salt was further enhanced by acid doping.",

author = "Jun Rao and R. Vijayaraghavan and Fangfang Chen and Haijin Zhu and Howlett, {Patrick C.} and Macfarlane, {Douglas R.} and Maria Forsyth",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6cc07154f",

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volume = "52",

pages = "14097--14100",

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T1 - Protic organic ionic plastic crystals based on a difunctional cation and the triflate anion

T2 - A new solid-state proton conductor

AU - Rao, Jun

AU - Vijayaraghavan, R.

AU - Chen, Fangfang

AU - Zhu, Haijin

AU - Howlett, Patrick C.

AU - Macfarlane, Douglas R.

AU - Forsyth, Maria

PY - 2016

Y1 - 2016

N2 - Two protic organic ionic plastic crystalline materials based on the mono- and di-protonated cations of N,N-dimethylethylenediamine, (DMEDA) and the triflate anion have been studied. The symmetrical di-protonated cation salt shows 54 °C higher melting point and 24-fold higher conductivity at room temperature as compared to the mono-protonated cation salt, making it a promising candidate for a solid-state proton conductor. The conductivity of this salt was further enhanced by acid doping.

AB - Two protic organic ionic plastic crystalline materials based on the mono- and di-protonated cations of N,N-dimethylethylenediamine, (DMEDA) and the triflate anion have been studied. The symmetrical di-protonated cation salt shows 54 °C higher melting point and 24-fold higher conductivity at room temperature as compared to the mono-protonated cation salt, making it a promising candidate for a solid-state proton conductor. The conductivity of this salt was further enhanced by acid doping.

UR - http://www.scopus.com/inward/record.url?scp=85000501017&partnerID=8YFLogxK

U2 - 10.1039/c6cc07154f

DO - 10.1039/c6cc07154f

M3 - 文章

AN - SCOPUS:85000501017

SN - 1359-7345

VL - 52

SP - 14097

EP - 14100

JO - Chemical Communications

JF - Chemical Communications

IS - 98

ER -

Protic organic ionic plastic crystals based on a difunctional cation and the triflate anion: A new solid-state proton conductor

Abstract

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