Piers' borane-mediated hydrosilylation of epoxides and cyclic ethers

Jianbo Zhang; Sehoon Park; Sukbok Chang

doi:10.1039/c8cc03741h

Piers' borane-mediated hydrosilylation of epoxides and cyclic ethers

Jianbo Zhang, Sehoon Park^*, Sukbok Chang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

We report the first diarylborane-catalysed hydrosilylation of epoxides and cyclic ethers. Mechanistic studies on the in situ generated Piers' borane (C₆F₅)₂BH with hydrosilanes in the presence of an epoxide revealed that an alkyloxy(diaryl)borane (C₆F₅)₂BOR is readily formed as a catalytically competent species for the outer-sphere hydrosilylation of epoxides and cyclic ethers.

Original language	English
Pages (from-to)	7243-7246
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	52
DOIs	https://doi.org/10.1039/c8cc03741h
State	Published - 2018
Externally published	Yes

Access to Document

10.1039/c8cc03741h

Cite this

@article{5e3f855ff2a449658b57fe663d48e782,

title = "Piers' borane-mediated hydrosilylation of epoxides and cyclic ethers",

abstract = "We report the first diarylborane-catalysed hydrosilylation of epoxides and cyclic ethers. Mechanistic studies on the in situ generated Piers' borane (C6F5)2BH with hydrosilanes in the presence of an epoxide revealed that an alkyloxy(diaryl)borane (C6F5)2BOR is readily formed as a catalytically competent species for the outer-sphere hydrosilylation of epoxides and cyclic ethers.",

author = "Jianbo Zhang and Sehoon Park and Sukbok Chang",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2018.",

year = "2018",

doi = "10.1039/c8cc03741h",

language = "英语",

volume = "54",

pages = "7243--7246",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "52",

}

TY - JOUR

T1 - Piers' borane-mediated hydrosilylation of epoxides and cyclic ethers

AU - Zhang, Jianbo

AU - Park, Sehoon

AU - Chang, Sukbok

N1 - Publisher Copyright: © The Royal Society of Chemistry 2018.

PY - 2018

Y1 - 2018

N2 - We report the first diarylborane-catalysed hydrosilylation of epoxides and cyclic ethers. Mechanistic studies on the in situ generated Piers' borane (C6F5)2BH with hydrosilanes in the presence of an epoxide revealed that an alkyloxy(diaryl)borane (C6F5)2BOR is readily formed as a catalytically competent species for the outer-sphere hydrosilylation of epoxides and cyclic ethers.

AB - We report the first diarylborane-catalysed hydrosilylation of epoxides and cyclic ethers. Mechanistic studies on the in situ generated Piers' borane (C6F5)2BH with hydrosilanes in the presence of an epoxide revealed that an alkyloxy(diaryl)borane (C6F5)2BOR is readily formed as a catalytically competent species for the outer-sphere hydrosilylation of epoxides and cyclic ethers.

UR - http://www.scopus.com/inward/record.url?scp=85049195024&partnerID=8YFLogxK

U2 - 10.1039/c8cc03741h

DO - 10.1039/c8cc03741h

M3 - 文章

C2 - 29901036

AN - SCOPUS:85049195024

SN - 1359-7345

VL - 54

SP - 7243

EP - 7246

JO - Chemical Communications

JF - Chemical Communications

IS - 52

ER -

Piers' borane-mediated hydrosilylation of epoxides and cyclic ethers

Abstract

Access to Document

Other files and links

Fingerprint

Cite this