Abstract
By preventing electrical contact between anode and cathode electrodes while promoting ionic transport, separators are critical components in the safe operation of rechargeable battery technologies. However, traditional polymer-based separators have limited thermal stability, which has contributed to catastrophic thermal runaway failure modes that have conspicuously plagued lithium-ion batteries. Here, we describe the development of phase-inversion composite separators based on carbon-coated hexagonal boron nitride (hBN) nanosheets and poly(vinylidene fluoride) (PVDF) polymers that possess high porosity, electrolyte wettability, and thermal stability. The carbon-coated hBN nanosheets are obtained through a scalable liquid-phase shear exfoliation method using ethyl cellulose as a polymer stabilizer and source of the carbon coating following thermal pyrolysis. When incorporated within the PVDF matrix, the carbon-coated hBN nanosheets promote favorable interfacial interactions during the phase-inversion process, resulting in porous, flexible, free-standing composite separators. The unique chemical composition of these carbon-coated hBN separators implies high wettability for a wide range of liquid electrolytes. This combination of high porosity and electrolyte wettability enables enhanced ionic conductivity and lithium-ion battery electrochemical performance that exceeds incumbent polyolefin separators over a wide range of operating conditions. The hBN nanosheets also impart high thermal stability, providing safe lithium-ion battery operation up to 120 °C.
| Original language | English |
|---|---|
| Pages (from-to) | 8107-8114 |
| Number of pages | 8 |
| Journal | ACS applied materials & interfaces |
| Volume | 12 |
| Issue number | 7 |
| DOIs | |
| State | Published - 19 Feb 2020 |
| Externally published | Yes |
Keywords
- hexagonal boron nitride
- lithium-ion battery
- phase-inversion
- polymer composite
- separator
