Pd-catalyzed selective cyclopolymerization of α,ω-dienes and copolymerization with α-olefins

TY - CONF

T1 - Pd-catalyzed selective cyclopolymerization of α,ω-dienes and copolymerization with α-olefins

AU - Park, Sehoon

AU - Takeuchi, Daisuke

AU - Osakada, Kohtaro

PY - 2006

Y1 - 2006

N2 - Functionalized α,ω-dienes undergo cyclopolymerization to afford the polymer containing trans-fused five-membered rings. Various dienes including diallyl malonates and diallyl amines are usable for the cyclopolymerization. Copolymerization of dienes with ethylene and α-olefins using Pd complexes produces the copolymer containing five-membered rings. The NMR of poly(l-co-hexene) showed selective insertion mode of the dienes and 1-hexene. The insertion and cyclization of the diene in the copolymerization takes place analogously to those in the homopolymerization.

AB - Functionalized α,ω-dienes undergo cyclopolymerization to afford the polymer containing trans-fused five-membered rings. Various dienes including diallyl malonates and diallyl amines are usable for the cyclopolymerization. Copolymerization of dienes with ethylene and α-olefins using Pd complexes produces the copolymer containing five-membered rings. The NMR of poly(l-co-hexene) showed selective insertion mode of the dienes and 1-hexene. The insertion and cyclization of the diene in the copolymerization takes place analogously to those in the homopolymerization.

KW - Cyclopolymerization

KW - Pd catalysts

KW - Terpolymerization

KW - α,ω-dienes

UR - http://www.scopus.com/inward/record.url?scp=33846139622&partnerID=8YFLogxK

M3 - 论文

AN - SCOPUS:33846139622

SP - 2703

EP - 2704

T2 - 55th Society of Polymer Science Japan Symposium on Macromolecules

Y2 - 20 September 2006 through 22 September 2006

ER -