Organometallic Molecule-Inorganic Surface Coordination and Catalytic Chemistry. Facile and Selective Alkane Activation by Supported Tetraallylthorium

Moris S. Eisen; Tobin J. Marks

doi:10.1021/om00060a006

Organometallic Molecule-Inorganic Surface Coordination and Catalytic Chemistry. Facile and Selective Alkane Activation by Supported Tetraallylthorium

Moris S. Eisen, Tobin J. Marks^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

The adsorption of Th(η³-allyl)₄ on dehydroxylated alumina yields an active catalyst for the exchange of alkane and cycloalkane C-H bonds with D₂. C-H reactivities fall in the order primary > secondary > tertiary and less sterically hindered > more sterlcally hindered.

Original language	English
Pages (from-to)	3939-3941
Number of pages	3
Journal	Organometallics
Volume	11
Issue number	12
DOIs	https://doi.org/10.1021/om00060a006
State	Published - 1 Dec 1992
Externally published	Yes

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title = "Organometallic Molecule-Inorganic Surface Coordination and Catalytic Chemistry. Facile and Selective Alkane Activation by Supported Tetraallylthorium",

abstract = "The adsorption of Th(η3-allyl)4 on dehydroxylated alumina yields an active catalyst for the exchange of alkane and cycloalkane C-H bonds with D2. C-H reactivities fall in the order primary > secondary > tertiary and less sterically hindered > more sterlcally hindered.",

author = "Eisen, {Moris S.} and Marks, {Tobin J.}",

year = "1992",

month = dec,

day = "1",

doi = "10.1021/om00060a006",

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volume = "11",

pages = "3939--3941",

journal = "Organometallics",

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T1 - Organometallic Molecule-Inorganic Surface Coordination and Catalytic Chemistry. Facile and Selective Alkane Activation by Supported Tetraallylthorium

AU - Eisen, Moris S.

AU - Marks, Tobin J.

PY - 1992/12/1

Y1 - 1992/12/1

N2 - The adsorption of Th(η3-allyl)4 on dehydroxylated alumina yields an active catalyst for the exchange of alkane and cycloalkane C-H bonds with D2. C-H reactivities fall in the order primary > secondary > tertiary and less sterically hindered > more sterlcally hindered.

AB - The adsorption of Th(η3-allyl)4 on dehydroxylated alumina yields an active catalyst for the exchange of alkane and cycloalkane C-H bonds with D2. C-H reactivities fall in the order primary > secondary > tertiary and less sterically hindered > more sterlcally hindered.

UR - http://www.scopus.com/inward/record.url?scp=0001208293&partnerID=8YFLogxK

U2 - 10.1021/om00060a006

DO - 10.1021/om00060a006

M3 - 文章

AN - SCOPUS:0001208293

SN - 0276-7333

VL - 11

SP - 3939

EP - 3941

JO - Organometallics

JF - Organometallics

IS - 12

ER -

Organometallic Molecule-Inorganic Surface Coordination and Catalytic Chemistry. Facile and Selective Alkane Activation by Supported Tetraallylthorium

Abstract

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