Gram-size Pt/C catalyst synthesized using Pt compound directly recovered from an end-of-life PEM fuel cell stack

TY - JOUR

T1 - Gram-size Pt/C catalyst synthesized using Pt compound directly recovered from an end-of-life PEM fuel cell stack

AU - Chourashiya, Muralidhar

AU - Sharma, Raghunandan

AU - Gyergyek, Saso

AU - Andersen, Shuang Ma

PY - 2022/1/15

Y1 - 2022/1/15

N2 - The proton exchange membrane fuel cell (PEMFC) technology is getting closer to its maturity. However, the use of PEMFCs in fuel cell vehicles needs to tackle the challenges arising from insufficient durability and the high cost of catalysts, leading to the accumulation of high-price waste from the end-of-life fuel cell stacks. The use of this waste as a secondary source of platinum can be more economic and environmentally friendly compared to its primary production. In this investigation, platinum from the end-of-life fuel cell stack is recycled as a fresh Pt/C catalyst. The recycling processes involved the dissolution of Pt from the end-of-life fuel cell electrodes by refluxing in dilute acid (1 M HCl), followed by drying the Pt solution in a rotary evaporator and using the dried-Pt precursor for polyol synthesis of Pt/C. With the aim of their industrial adaptation, a gram-scale synthesis of Pt/C using the polyol method is carried out and its electrocatalytic performance is compared with commercial benchmark catalysts. Electrochemical performances of the Pt/C electrocatalysts synthesized using the recycled Pt and the equivalent commercial Pt precursor are found to be comparable.

AB - The proton exchange membrane fuel cell (PEMFC) technology is getting closer to its maturity. However, the use of PEMFCs in fuel cell vehicles needs to tackle the challenges arising from insufficient durability and the high cost of catalysts, leading to the accumulation of high-price waste from the end-of-life fuel cell stacks. The use of this waste as a secondary source of platinum can be more economic and environmentally friendly compared to its primary production. In this investigation, platinum from the end-of-life fuel cell stack is recycled as a fresh Pt/C catalyst. The recycling processes involved the dissolution of Pt from the end-of-life fuel cell electrodes by refluxing in dilute acid (1 M HCl), followed by drying the Pt solution in a rotary evaporator and using the dried-Pt precursor for polyol synthesis of Pt/C. With the aim of their industrial adaptation, a gram-scale synthesis of Pt/C using the polyol method is carried out and its electrocatalytic performance is compared with commercial benchmark catalysts. Electrochemical performances of the Pt/C electrocatalysts synthesized using the recycled Pt and the equivalent commercial Pt precursor are found to be comparable.

KW - End-of-life fuel cells

KW - Pt recovery

KW - Recycling

KW - Pt/C electrocatalyst

KW - Polyol synthesis

U2 - 10.1016/j.matchemphys.2021.125439

DO - 10.1016/j.matchemphys.2021.125439

M3 - 文章

SN - 0254-0584

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

ER -