Formation of Inclusion Organoactinide Complexes with Boron-Containing Macrocycles

Eyal Barnea; Tamer Andrea; Moshe Kapon; Moris S. Eisen

doi:10.1021/ja0498843

Formation of Inclusion Organoactinide Complexes with Boron-Containing Macrocycles

Eyal Barnea, Tamer Andrea, Moshe Kapon, Moris S. Eisen^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

Reaction of the organoactinide complexes (C₅Me₅)₂AnMe₂ (An = Th, U) with catecholborane yields an inclusion complex where the actinide is encapsulated inside a 15-membered, hexaoxo, trianionic macrocycle built from alternating catechol and catecholborate fragments. In the presence of LiOH, a dimer of two encapsulated actinide macrocycles is formed. The X-ray molecular structure for all the complexes is presented.

Original language	English
Pages (from-to)	5066-5067
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	126
Issue number	16
DOIs	https://doi.org/10.1021/ja0498843
State	Published - 28 Apr 2004
Externally published	Yes

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abstract = "Reaction of the organoactinide complexes (C5Me5)2AnMe2 (An = Th, U) with catecholborane yields an inclusion complex where the actinide is encapsulated inside a 15-membered, hexaoxo, trianionic macrocycle built from alternating catechol and catecholborate fragments. In the presence of LiOH, a dimer of two encapsulated actinide macrocycles is formed. The X-ray molecular structure for all the complexes is presented.",

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AU - Barnea, Eyal

AU - Andrea, Tamer

AU - Kapon, Moshe

AU - Eisen, Moris S.

PY - 2004/4/28

Y1 - 2004/4/28

N2 - Reaction of the organoactinide complexes (C5Me5)2AnMe2 (An = Th, U) with catecholborane yields an inclusion complex where the actinide is encapsulated inside a 15-membered, hexaoxo, trianionic macrocycle built from alternating catechol and catecholborate fragments. In the presence of LiOH, a dimer of two encapsulated actinide macrocycles is formed. The X-ray molecular structure for all the complexes is presented.

AB - Reaction of the organoactinide complexes (C5Me5)2AnMe2 (An = Th, U) with catecholborane yields an inclusion complex where the actinide is encapsulated inside a 15-membered, hexaoxo, trianionic macrocycle built from alternating catechol and catecholborate fragments. In the presence of LiOH, a dimer of two encapsulated actinide macrocycles is formed. The X-ray molecular structure for all the complexes is presented.

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Formation of Inclusion Organoactinide Complexes with Boron-Containing Macrocycles

Abstract

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