Fabrication of Amine and Zirconia on MCM-41 as Acid–Base Catalysts for the Fixation of Carbon Dioxide

Vitthal B. Saptal; Binita Nanda; Kulamani M. Parida; Bhalchandra M. Bhanage

doi:10.1002/cctc.201700656

Fabrication of Amine and Zirconia on MCM-41 as Acid–Base Catalysts for the Fixation of Carbon Dioxide

Vitthal B. Saptal, Binita Nanda, Kulamani M. Parida^*, Bhalchandra M. Bhanage

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Highly porous catalysts based on MCM-41 with both acidic and basic sites such as ZrO₂ as an acid and (3-aminopropyl)triethoxysilane as a mild base are fabricated and characterized thoroughly by using XRD, SEM, thermogravimetric analysis, temperature-programmed reduction, desorption, oxidation, BET surface area analysis, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and IR spectroscopy. This catalyst shows a synergistic effect for the activation of epoxide as well as CO₂ to synthesize cyclic carbonates. The presence of the free amine functional group activates CO₂ by absorption, whereas the presence of Zr metal activates the epoxide ring. The effect of the amine and catalyst loading on the cycloaddition reaction was studied. Additionally, the cycloaddition reaction proceeds under solvent-free and mild conditions, and the catalysts are recyclable.

Original language	English
Pages (from-to)	4105-4111
Number of pages	7
Journal	ChemCatChem
Volume	9
Issue number	21
DOIs	https://doi.org/10.1002/cctc.201700656
State	Published - 9 Nov 2017
Externally published	Yes

Keywords

CO fixation
amines
cycloaddition
mesoporous materials
zirconium

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title = "Fabrication of Amine and Zirconia on MCM-41 as Acid–Base Catalysts for the Fixation of Carbon Dioxide",

abstract = "Highly porous catalysts based on MCM-41 with both acidic and basic sites such as ZrO2 as an acid and (3-aminopropyl)triethoxysilane as a mild base are fabricated and characterized thoroughly by using XRD, SEM, thermogravimetric analysis, temperature-programmed reduction, desorption, oxidation, BET surface area analysis, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and IR spectroscopy. This catalyst shows a synergistic effect for the activation of epoxide as well as CO2 to synthesize cyclic carbonates. The presence of the free amine functional group activates CO2 by absorption, whereas the presence of Zr metal activates the epoxide ring. The effect of the amine and catalyst loading on the cycloaddition reaction was studied. Additionally, the cycloaddition reaction proceeds under solvent-free and mild conditions, and the catalysts are recyclable.",

keywords = "CO fixation, amines, cycloaddition, mesoporous materials, zirconium",

author = "Saptal, {Vitthal B.} and Binita Nanda and Parida, {Kulamani M.} and Bhanage, {Bhalchandra M.}",

note = "Publisher Copyright: {\textcopyright} 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.",

year = "2017",

month = nov,

day = "9",

doi = "10.1002/cctc.201700656",

language = "英语",

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AU - Saptal, Vitthal B.

AU - Nanda, Binita

AU - Parida, Kulamani M.

AU - Bhanage, Bhalchandra M.

PY - 2017/11/9

Y1 - 2017/11/9

N2 - Highly porous catalysts based on MCM-41 with both acidic and basic sites such as ZrO2 as an acid and (3-aminopropyl)triethoxysilane as a mild base are fabricated and characterized thoroughly by using XRD, SEM, thermogravimetric analysis, temperature-programmed reduction, desorption, oxidation, BET surface area analysis, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and IR spectroscopy. This catalyst shows a synergistic effect for the activation of epoxide as well as CO2 to synthesize cyclic carbonates. The presence of the free amine functional group activates CO2 by absorption, whereas the presence of Zr metal activates the epoxide ring. The effect of the amine and catalyst loading on the cycloaddition reaction was studied. Additionally, the cycloaddition reaction proceeds under solvent-free and mild conditions, and the catalysts are recyclable.

AB - Highly porous catalysts based on MCM-41 with both acidic and basic sites such as ZrO2 as an acid and (3-aminopropyl)triethoxysilane as a mild base are fabricated and characterized thoroughly by using XRD, SEM, thermogravimetric analysis, temperature-programmed reduction, desorption, oxidation, BET surface area analysis, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and IR spectroscopy. This catalyst shows a synergistic effect for the activation of epoxide as well as CO2 to synthesize cyclic carbonates. The presence of the free amine functional group activates CO2 by absorption, whereas the presence of Zr metal activates the epoxide ring. The effect of the amine and catalyst loading on the cycloaddition reaction was studied. Additionally, the cycloaddition reaction proceeds under solvent-free and mild conditions, and the catalysts are recyclable.

KW - CO fixation

KW - amines

KW - cycloaddition

KW - mesoporous materials

KW - zirconium

UR - http://www.scopus.com/inward/record.url?scp=85030539541&partnerID=8YFLogxK

U2 - 10.1002/cctc.201700656

DO - 10.1002/cctc.201700656

M3 - 文章

AN - SCOPUS:85030539541

SN - 1867-3880

VL - 9

SP - 4105

EP - 4111

JO - ChemCatChem

JF - ChemCatChem

IS - 21

ER -

Fabrication of Amine and Zirconia on MCM-41 as Acid–Base Catalysts for the Fixation of Carbon Dioxide

Abstract

Keywords

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