Enlarged reactive cone of acceptance upon vibrational excitation: O(3P) + HCl

I. Schechter; R. D. Levine

doi:10.1021/j100361a003

Enlarged reactive cone of acceptance upon vibrational excitation: O(³P) + HCl

I. Schechter, R. D. Levine^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Enhanced reactive asymmetry for reaction upon reagent vibrational excitation has been predicted for a number of A + HB reactions. If correct, it provides a new mechanism for vibrationally enhanced reactivity. This mechanism does not necessarily require a potential energy surface with a late barrier for reaction. Rather, the required condition is a low symmetric stretch frequency at the saddle point as compared to the vibrational frequency of the reagent. The O(³P) + HCl → OH + Cl reaction can provide an experimental test of this predicted enhancement.

Original language	English
Pages (from-to)	7973-7975
Number of pages	3
Journal	Journal of Physical Chemistry
Volume	93
Issue number	24
DOIs	https://doi.org/10.1021/j100361a003
State	Published - 1989
Externally published	Yes

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title = "Enlarged reactive cone of acceptance upon vibrational excitation: O(3P) + HCl",

abstract = "Enhanced reactive asymmetry for reaction upon reagent vibrational excitation has been predicted for a number of A + HB reactions. If correct, it provides a new mechanism for vibrationally enhanced reactivity. This mechanism does not necessarily require a potential energy surface with a late barrier for reaction. Rather, the required condition is a low symmetric stretch frequency at the saddle point as compared to the vibrational frequency of the reagent. The O(3P) + HCl → OH + Cl reaction can provide an experimental test of this predicted enhancement.",

author = "I. Schechter and Levine, {R. D.}",

year = "1989",

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N2 - Enhanced reactive asymmetry for reaction upon reagent vibrational excitation has been predicted for a number of A + HB reactions. If correct, it provides a new mechanism for vibrationally enhanced reactivity. This mechanism does not necessarily require a potential energy surface with a late barrier for reaction. Rather, the required condition is a low symmetric stretch frequency at the saddle point as compared to the vibrational frequency of the reagent. The O(3P) + HCl → OH + Cl reaction can provide an experimental test of this predicted enhancement.

AB - Enhanced reactive asymmetry for reaction upon reagent vibrational excitation has been predicted for a number of A + HB reactions. If correct, it provides a new mechanism for vibrationally enhanced reactivity. This mechanism does not necessarily require a potential energy surface with a late barrier for reaction. Rather, the required condition is a low symmetric stretch frequency at the saddle point as compared to the vibrational frequency of the reagent. The O(3P) + HCl → OH + Cl reaction can provide an experimental test of this predicted enhancement.

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DO - 10.1021/j100361a003

M3 - 文章

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JO - Journal of Physical Chemistry

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ER -

Enlarged reactive cone of acceptance upon vibrational excitation: O(³P) + HCl

Abstract

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