Dependence of structure-property relations on substituent distributions in lead zirconate titanate

Qi Tan; Z. Xu; Dwight Viehland

doi:10.1080/13642810008208586

Dependence of structure-property relations on substituent distributions in lead zirconate titanate

Qi Tan, Z. Xu, Dwight Viehland

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The dependence of substituent distributions on A and B sites in rhombohedral lead zirconate titanate (PZT) was investigated in terms of dielectric spectroscopy, polarization switching characteristics and transmission electron microscopy techniques. Decreasing the higher-valence A-site substituent radii resulted in higher coercive fields, a smaller decrease in transition temperatures and the disappearance of relaxor characteristics with respect to the largest A-site substituents La³⁺. These smaller substituents have enhanced the tendency to exchange on to B sites, resulting in an effective lower-valence substituent, “wavy” domain morphology and “hard” PZT properties.

Original language	English
Pages (from-to)	1585-1597
Number of pages	13
Journal	Philosophical Magazine B: Physics of Condensed Matter; Statistical Mechanics, Electronic, Optical and Magnetic Properties
Volume	80
Issue number	8
DOIs	https://doi.org/10.1080/13642810008208586
State	Published - Aug 2000
Externally published	Yes

Access to Document

10.1080/13642810008208586

Cite this

@article{aedbb92676774945aa18ebb9acd31faf,

title = "Dependence of structure-property relations on substituent distributions in lead zirconate titanate",

abstract = "The dependence of substituent distributions on A and B sites in rhombohedral lead zirconate titanate (PZT) was investigated in terms of dielectric spectroscopy, polarization switching characteristics and transmission electron microscopy techniques. Decreasing the higher-valence A-site substituent radii resulted in higher coercive fields, a smaller decrease in transition temperatures and the disappearance of relaxor characteristics with respect to the largest A-site substituents La3+. These smaller substituents have enhanced the tendency to exchange on to B sites, resulting in an effective lower-valence substituent, “wavy” domain morphology and “hard” PZT properties.",

author = "Qi Tan and Z. Xu and Dwight Viehland",

note = "Funding Information: ACKNOWLEDGEMENTS This work was supported by the Office of Naval Research under contract NO00 14-95-1 -0805 and by Naval Undersea Warfare Center contract N66604-95-C-1536. The use of the facilities at the Center for Microanalysis in the Materials Research Laboratory, University of Illinois at Urbana-Champaign, is gratefully acknowledged.",

year = "2000",

month = aug,

doi = "10.1080/13642810008208586",

language = "英语",

volume = "80",

pages = "1585--1597",

journal = "Philosophical Magazine B: Physics of Condensed Matter; Statistical Mechanics, Electronic, Optical and Magnetic Properties",

issn = "1364-2812",

publisher = "Taylor and Francis Ltd.",

number = "8",

}

Dependence of structure-property relations on substituent distributions in lead zirconate titanate. / Tan, Qi; Xu, Z.; Viehland, Dwight.
In: Philosophical Magazine B: Physics of Condensed Matter; Statistical Mechanics, Electronic, Optical and Magnetic Properties, Vol. 80, No. 8, 08.2000, p. 1585-1597.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Dependence of structure-property relations on substituent distributions in lead zirconate titanate

AU - Tan, Qi

AU - Xu, Z.

AU - Viehland, Dwight

N1 - Funding Information: ACKNOWLEDGEMENTS This work was supported by the Office of Naval Research under contract NO00 14-95-1 -0805 and by Naval Undersea Warfare Center contract N66604-95-C-1536. The use of the facilities at the Center for Microanalysis in the Materials Research Laboratory, University of Illinois at Urbana-Champaign, is gratefully acknowledged.

PY - 2000/8

Y1 - 2000/8

N2 - The dependence of substituent distributions on A and B sites in rhombohedral lead zirconate titanate (PZT) was investigated in terms of dielectric spectroscopy, polarization switching characteristics and transmission electron microscopy techniques. Decreasing the higher-valence A-site substituent radii resulted in higher coercive fields, a smaller decrease in transition temperatures and the disappearance of relaxor characteristics with respect to the largest A-site substituents La3+. These smaller substituents have enhanced the tendency to exchange on to B sites, resulting in an effective lower-valence substituent, “wavy” domain morphology and “hard” PZT properties.

AB - The dependence of substituent distributions on A and B sites in rhombohedral lead zirconate titanate (PZT) was investigated in terms of dielectric spectroscopy, polarization switching characteristics and transmission electron microscopy techniques. Decreasing the higher-valence A-site substituent radii resulted in higher coercive fields, a smaller decrease in transition temperatures and the disappearance of relaxor characteristics with respect to the largest A-site substituents La3+. These smaller substituents have enhanced the tendency to exchange on to B sites, resulting in an effective lower-valence substituent, “wavy” domain morphology and “hard” PZT properties.

UR - http://www.scopus.com/inward/record.url?scp=0034256718&partnerID=8YFLogxK

U2 - 10.1080/13642810008208586

DO - 10.1080/13642810008208586

M3 - 文章

AN - SCOPUS:0034256718

SN - 1364-2812

VL - 80

SP - 1585

EP - 1597

JO - Philosophical Magazine B: Physics of Condensed Matter; Statistical Mechanics, Electronic, Optical and Magnetic Properties

JF - Philosophical Magazine B: Physics of Condensed Matter; Statistical Mechanics, Electronic, Optical and Magnetic Properties

IS - 8

ER -

Dependence of structure-property relations on substituent distributions in lead zirconate titanate

Abstract

Access to Document

Other files and links

Fingerprint

Cite this