Catalytic organic transformations mediated by actinide complexes

Isabell S.R. Karmel; Rami J. Batrice; Moris S. Eisen

doi:10.3390/inorganics3040392

Catalytic organic transformations mediated by actinide complexes

Isabell S.R. Karmel, Rami J. Batrice, Moris S. Eisen^*

^*Corresponding author for this work

Research output: Contribution to journal › Review article › peer-review

30 Scopus citations

Abstract

This review article presents the development of organoactinides and actinide coordination complexes as catalysts for homogeneous organic transformations. This chapter introduces the basic principles of actinide catalysis and deals with the historic development of actinide complexes in catalytic processes. The application of organoactinides in homogeneous catalysis is exemplified in the hydroelementation reactions, such as the hydroamination, hydrosilylation, hydroalkoxylation and hydrothiolation of alkynes. Additionally, the use of actinide coordination complexes for the catalytic polymerization of a-olefins and the ring opening polymerization of cyclic esters is presented. The last part of this review article highlights novel catalytic transformations mediated by actinide compounds and gives an outlook to the further potential of this field.

Original language	English
Pages (from-to)	392-428
Number of pages	37
Journal	Inorganics
Volume	3
Issue number	4
DOIs	https://doi.org/10.3390/inorganics3040392
State	Published - 1 Dec 2015
Externally published	Yes

Keywords

Actinide coordination complexes
Activation of heterocumulenes
Homogeneous catalysis
Hydroelementations
Organoactinides
Polymerization of olefins
ROP

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title = "Catalytic organic transformations mediated by actinide complexes",

abstract = "This review article presents the development of organoactinides and actinide coordination complexes as catalysts for homogeneous organic transformations. This chapter introduces the basic principles of actinide catalysis and deals with the historic development of actinide complexes in catalytic processes. The application of organoactinides in homogeneous catalysis is exemplified in the hydroelementation reactions, such as the hydroamination, hydrosilylation, hydroalkoxylation and hydrothiolation of alkynes. Additionally, the use of actinide coordination complexes for the catalytic polymerization of a-olefins and the ring opening polymerization of cyclic esters is presented. The last part of this review article highlights novel catalytic transformations mediated by actinide compounds and gives an outlook to the further potential of this field.",

keywords = "Actinide coordination complexes, Activation of heterocumulenes, Homogeneous catalysis, Hydroelementations, Organoactinides, Polymerization of olefins, ROP",

author = "Karmel, {Isabell S.R.} and Batrice, {Rami J.} and Eisen, {Moris S.}",

note = "Publisher Copyright: {\textcopyright} 2015 by the authors.",

year = "2015",

month = dec,

day = "1",

doi = "10.3390/inorganics3040392",

language = "英语",

volume = "3",

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journal = "Inorganics",

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TY - JOUR

T1 - Catalytic organic transformations mediated by actinide complexes

AU - Karmel, Isabell S.R.

AU - Batrice, Rami J.

AU - Eisen, Moris S.

PY - 2015/12/1

Y1 - 2015/12/1

N2 - This review article presents the development of organoactinides and actinide coordination complexes as catalysts for homogeneous organic transformations. This chapter introduces the basic principles of actinide catalysis and deals with the historic development of actinide complexes in catalytic processes. The application of organoactinides in homogeneous catalysis is exemplified in the hydroelementation reactions, such as the hydroamination, hydrosilylation, hydroalkoxylation and hydrothiolation of alkynes. Additionally, the use of actinide coordination complexes for the catalytic polymerization of a-olefins and the ring opening polymerization of cyclic esters is presented. The last part of this review article highlights novel catalytic transformations mediated by actinide compounds and gives an outlook to the further potential of this field.

AB - This review article presents the development of organoactinides and actinide coordination complexes as catalysts for homogeneous organic transformations. This chapter introduces the basic principles of actinide catalysis and deals with the historic development of actinide complexes in catalytic processes. The application of organoactinides in homogeneous catalysis is exemplified in the hydroelementation reactions, such as the hydroamination, hydrosilylation, hydroalkoxylation and hydrothiolation of alkynes. Additionally, the use of actinide coordination complexes for the catalytic polymerization of a-olefins and the ring opening polymerization of cyclic esters is presented. The last part of this review article highlights novel catalytic transformations mediated by actinide compounds and gives an outlook to the further potential of this field.

KW - Actinide coordination complexes

KW - Activation of heterocumulenes

KW - Homogeneous catalysis

KW - Hydroelementations

KW - Organoactinides

KW - Polymerization of olefins

KW - ROP

UR - http://www.scopus.com/inward/record.url?scp=84976267890&partnerID=8YFLogxK

U2 - 10.3390/inorganics3040392

DO - 10.3390/inorganics3040392

M3 - 文献综述

AN - SCOPUS:84976267890

SN - 2304-6740

VL - 3

SP - 392

EP - 428

JO - Inorganics

JF - Inorganics

IS - 4

ER -

Catalytic organic transformations mediated by actinide complexes

Abstract

Keywords

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