Abstract
The octahedral titanium catalyst Ti(Ph2-PNpy) 2(NEt2)2 (1) was found to be an efficient catalyst for the hydroamination of methylenecyclopropane with either aromatic or aliphatic amines. For a symmetrical methylenecyclopropane, only one product is obtained in high yield. The reaction of complex 1 with ethylamine and aniline produces the dimeric titanium complexes Ti2(Ph2PN py)2(μ-NEt)2 and Ti2(Ph 2PNpy)2(μ-NPh)2, respectively.
Original language | English |
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Pages (from-to) | 5495-5498 |
Number of pages | 4 |
Journal | Organometallics |
Volume | 24 |
Issue number | 23 |
DOIs | |
State | Published - 7 Nov 2005 |
Externally published | Yes |