Catalytic Addition of Alcohols into Carbodiimides Promoted by Organoactinide Complexes

Heng Liu; Maxim Khononov; Natalia Fridman; Matthias Tamm; Moris S. Eisen

doi:10.1021/acs.inorgchem.7b00357

Catalytic Addition of Alcohols into Carbodiimides Promoted by Organoactinide Complexes

Heng Liu, Maxim Khononov, Natalia Fridman, Matthias Tamm^*, Moris S. Eisen

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The insertion of alcohols into carbodiimides mediated by benzimidazolin-2-iminato actinide complexes [(Bim^R₁/R₂N)AnN₃] [N = N(SiMe₃)₂] is presented herein. Analysis of single-crystal data revealed that steric hindrance, rather than electronic properties, plays an important role in determining the accessibility for this insertion process. All actinide complexes showed excellent activities under very mild conditions. Stoichiometric reactions in combination with kinetic and thermodynamic studies allow us to propose a plausible active species and a mechanism for the catalytic cycle.

Original language	English
Pages (from-to)	3153-3157
Number of pages	5
Journal	Inorganic Chemistry
Volume	56
Issue number	6
DOIs	https://doi.org/10.1021/acs.inorgchem.7b00357
State	Published - 20 Mar 2017
Externally published	Yes

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title = "Catalytic Addition of Alcohols into Carbodiimides Promoted by Organoactinide Complexes",

abstract = "The insertion of alcohols into carbodiimides mediated by benzimidazolin-2-iminato actinide complexes [(BimR1/R2N)AnN3] [N = N(SiMe3)2] is presented herein. Analysis of single-crystal data revealed that steric hindrance, rather than electronic properties, plays an important role in determining the accessibility for this insertion process. All actinide complexes showed excellent activities under very mild conditions. Stoichiometric reactions in combination with kinetic and thermodynamic studies allow us to propose a plausible active species and a mechanism for the catalytic cycle.",

author = "Heng Liu and Maxim Khononov and Natalia Fridman and Matthias Tamm and Eisen, {Moris S.}",

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T1 - Catalytic Addition of Alcohols into Carbodiimides Promoted by Organoactinide Complexes

AU - Liu, Heng

AU - Khononov, Maxim

AU - Fridman, Natalia

AU - Tamm, Matthias

AU - Eisen, Moris S.

PY - 2017/3/20

Y1 - 2017/3/20

N2 - The insertion of alcohols into carbodiimides mediated by benzimidazolin-2-iminato actinide complexes [(BimR1/R2N)AnN3] [N = N(SiMe3)2] is presented herein. Analysis of single-crystal data revealed that steric hindrance, rather than electronic properties, plays an important role in determining the accessibility for this insertion process. All actinide complexes showed excellent activities under very mild conditions. Stoichiometric reactions in combination with kinetic and thermodynamic studies allow us to propose a plausible active species and a mechanism for the catalytic cycle.

AB - The insertion of alcohols into carbodiimides mediated by benzimidazolin-2-iminato actinide complexes [(BimR1/R2N)AnN3] [N = N(SiMe3)2] is presented herein. Analysis of single-crystal data revealed that steric hindrance, rather than electronic properties, plays an important role in determining the accessibility for this insertion process. All actinide complexes showed excellent activities under very mild conditions. Stoichiometric reactions in combination with kinetic and thermodynamic studies allow us to propose a plausible active species and a mechanism for the catalytic cycle.

UR - http://www.scopus.com/inward/record.url?scp=85015728356&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.7b00357

DO - 10.1021/acs.inorgchem.7b00357

M3 - 文章

C2 - 28271883

AN - SCOPUS:85015728356

SN - 0020-1669

VL - 56

SP - 3153

EP - 3157

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 6

ER -

Catalytic Addition of Alcohols into Carbodiimides Promoted by Organoactinide Complexes

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