Adsorbate alignment in surface halogenation: Standing up is better than lying down

Kai Huang; Iain R. McNab; John C. Polanyi; Jody Yang

doi:10.1002/anie.201202772

Adsorbate alignment in surface halogenation: Standing up is better than lying down

Kai Huang, Iain R. McNab, John C. Polanyi^*, Jody Yang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Bromine atom transfer to a silicon surface as a function of physisorbed adsorbate alignment (see picture: left, vertical 1-bromopentane; right, horizontal 1-bromopentane) of 1-bromopropane and 1-bromopentane on Si(111)-7×7 has been studied by STM. In both thermal and electron-induced bromination reactions, the vertical alignment is more reactive.

Original language	English
Pages (from-to)	9061-9065
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	36
DOIs	https://doi.org/10.1002/anie.201202772
State	Published - 3 Sep 2012
Externally published	Yes

Keywords

ab initio calculations
haloalkanes
reaction dynamics
scanning probe microscopy
silicon

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10.1002/anie.201202772

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title = "Adsorbate alignment in surface halogenation: Standing up is better than lying down",

abstract = "Bromine atom transfer to a silicon surface as a function of physisorbed adsorbate alignment (see picture: left, vertical 1-bromopentane; right, horizontal 1-bromopentane) of 1-bromopropane and 1-bromopentane on Si(111)-7×7 has been studied by STM. In both thermal and electron-induced bromination reactions, the vertical alignment is more reactive.",

keywords = "ab initio calculations, haloalkanes, reaction dynamics, scanning probe microscopy, silicon",

author = "Kai Huang and McNab, {Iain R.} and Polanyi, {John C.} and Jody Yang",

year = "2012",

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doi = "10.1002/anie.201202772",

language = "英语",

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T1 - Adsorbate alignment in surface halogenation

T2 - Standing up is better than lying down

AU - Huang, Kai

AU - McNab, Iain R.

AU - Polanyi, John C.

AU - Yang, Jody

PY - 2012/9/3

Y1 - 2012/9/3

N2 - Bromine atom transfer to a silicon surface as a function of physisorbed adsorbate alignment (see picture: left, vertical 1-bromopentane; right, horizontal 1-bromopentane) of 1-bromopropane and 1-bromopentane on Si(111)-7×7 has been studied by STM. In both thermal and electron-induced bromination reactions, the vertical alignment is more reactive.

AB - Bromine atom transfer to a silicon surface as a function of physisorbed adsorbate alignment (see picture: left, vertical 1-bromopentane; right, horizontal 1-bromopentane) of 1-bromopropane and 1-bromopentane on Si(111)-7×7 has been studied by STM. In both thermal and electron-induced bromination reactions, the vertical alignment is more reactive.

KW - ab initio calculations

KW - haloalkanes

KW - reaction dynamics

KW - scanning probe microscopy

KW - silicon

UR - http://www.scopus.com/inward/record.url?scp=84865856312&partnerID=8YFLogxK

U2 - 10.1002/anie.201202772

DO - 10.1002/anie.201202772

M3 - 文章

C2 - 22865591

AN - SCOPUS:84865856312

SN - 1433-7851

VL - 51

SP - 9061

EP - 9065

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 36

ER -

Adsorbate alignment in surface halogenation: Standing up is better than lying down

Abstract

Keywords

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