Abstract
Bromine atom transfer to a silicon surface as a function of physisorbed adsorbate alignment (see picture: left, vertical 1-bromopentane; right, horizontal 1-bromopentane) of 1-bromopropane and 1-bromopentane on Si(111)-7×7 has been studied by STM. In both thermal and electron-induced bromination reactions, the vertical alignment is more reactive.
Original language | English |
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Pages (from-to) | 9061-9065 |
Number of pages | 5 |
Journal | Angewandte Chemie - International Edition |
Volume | 51 |
Issue number | 36 |
DOIs | |
State | Published - 3 Sep 2012 |
Externally published | Yes |
Keywords
- ab initio calculations
- haloalkanes
- reaction dynamics
- scanning probe microscopy
- silicon